| Identification | Back Directory | [Name]
Pyrrolidine, 2-[diphenyl[(trimethylsilyl)oxy]methyl]-, (2R)- | [CAS]
943757-71-9 | [Synonyms]
(R)-Hayashi-Jorgensen Catalyst
R-Diphenylprolinol trimethyl silyl ether
α,α-Diphenyl-D-prolinol Trimethylsilyl Ether
(diphenyl(trimethylsilyloxy)methyl)pyrrolidine
(R)-Diphenylprolinol Trimethyl Silyl Ether,99%e.e.
alpha,alpha-Diphenyl-D-prolinol Trimethylsilyl Ether
(R)-2-[Diphenyl(trimethylsilanyloxy)methyl]pyrrolidine
(2R)-2-[Diphenyl[(trimethylsilyl)oxy]methyl]pyrrolidine
[diphenyl-[(2R)-pyrrolidin-2-yl]methoxy]-trimethylsilane
(R)-Diphenylprolinol trimethyl silyl ether, 95% (99% ee)
Pyrrolidine, 2-[diphenyl[(trimethylsilyl)oxy]methyl]-, (2R)-
(R)-(+)-a,a-Diphenyl-2-pyrrolidineMethanol TriMethylsilyl Ether
(R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether
(R)-(+)-α,α-Diphenyl-2-pyrrolidineMethanol triMethylsilyl ether 96%
(R)-(+)-alpha,alpha-Diphenyl-2-pyrrolidinemethanol Trimethylsilyl Ether
(R)-(+)-alpha,alpha-Diphenyl-2-pyrrolidineMethanol triMethylsilyl ether 96%
(R)-(+)-alpha,alpha-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether solution | [Molecular Formula]
C20H27NOSi | [MDL Number]
MFCD09265100 | [MOL File]
943757-71-9.mol | [Molecular Weight]
325.525 |
| Chemical Properties | Back Directory | [Boiling point ]
412.7±35.0 °C(Predicted) | [density ]
1.021 | [refractive index ]
n20/D1.5509 | [Fp ]
>110℃ | [storage temp. ]
2-8°C | [form ]
clear liquid | [pka]
10.01±0.10(Predicted) | [color ]
Light orange to Yellow to Green | [Optical Rotation]
[α]22/D +52±5°, c = 1 in chloroform | [InChI]
InChI=1S/C20H27NOSi/c1-23(2,3)22-20(19-15-10-16-21-19,17-11-6-4-7-12-17)18-13-8-5-9-14-18/h4-9,11-14,19,21H,10,15-16H2,1-3H3/t19-/m1/s1 | [InChIKey]
RSUHWMSTWSSNOW-LJQANCHMSA-N | [SMILES]
N1CCC[C@@H]1C(C1=CC=CC=C1)(C1=CC=CC=C1)O[Si](C)(C)C |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
36/37/38 | [Safety Statements ]
26 | [WGK Germany ]
3 | [HS Code ]
2933.99.8290 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
(R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether can be used as a catalyst to synthesize:
- Glycofused tricyclic derivatives, which are used in the development of amyloid β-peptide diagnostic tools.
- Cyclohexene carbaldehyde derivatives by reacting benzoylnitromethane with aliphatic enals.
| [General Description]
(R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether is a diarylprolinol silyl ether organocatalyst. |
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