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958261-50-2

958261-50-2 Structure

958261-50-2 Structure
IdentificationBack Directory
[Name]

Poly[[9-(1-octylnonyl)-9H-carbazole-2,7-diyl]-2,5-thiophenediyl-2,1,3-benzothiadiazole-4,7-diyl-2,5-thiophenediyl]
[CAS]

958261-50-2
[Synonyms]

PCDTBT
Poly[N-9'-heptadecanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)]
Poly[[9-(1-octylnonyl)-9H-carbazole-2,7-diyl]-2,5-thiophenediyl-2,1,3-benzothiadiazole-4,7-diyl-2,5-thiophenediyl]
[Molecular Formula]

(C43H47N3S3)n
[MOL File]

958261-50-2.mol
Chemical PropertiesBack Directory
[Melting point ]

270-300°C
[density ]

1.33 g/cm3 (amorphous)
[form ]

solid
[semiconductor properties]

P-type (mobility=6×10-5cm2/V·s)
[λmax]

576 nm
[CAS DataBase Reference]

958261-50-2
[solubility ]

Chloroform, chlorobenzene, dichlorobenzene and trichlorobenzene
Hazard InformationBack Directory
[Description]

Poly[N-9′-hepta-decanyl-2,7-carbazole-alt-5-5-(4′,7′-di-2-thienyl-2′,1′,3′-benzothiadiazole)] (PCDTBT) is a stable semiconducting polymer with high rigidity in its molecular chains, which makes it difficult to organize into an ordered structure and affects the device performance.  A PCDTBT network consisting of aggregates and nanofibers in thin films was fabricated through the phase separation of mixed PCDTBT and polyethylene glycol (PEG). [1]
[Uses]

PCDTBT blend with PCBM as a nanocomposite can be used as a donor/acceptor material for the fabrication of photovoltaic solar cells and photovoltaic inks. It may also be used as an active layer that can be used in the development of organic field effect transistors (OFETs) for the parts per million (ppm) level detection of NO2 gas.
[References]

[1] XU J, LIU Z, JING L, et al. Fabrication of PCDTBT Conductive Network via Phase Separation[J]. Materials, 2021, 14. DOI:10.3390/ma14175071.
Safety DataBack Directory
[WGK Germany ]

3
[HS Code ]

39119000
Questions And AnswerBack Directory
[Classification]

Polycarbazoles, Heterocyclic five-membered ring, Organic semiconducting materials, Low band gap polymers, Organic photovoltaics, Polymer solar cells, OFETs and Perovskite solar cells.
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