| Identification | Back Directory | [Name]
(8α,9S)-9-aMino-Cinchonan-6'-ol | [CAS]
960050-59-3 | [Synonyms]
(8α,9S)-9-aMino-Cinchonan-6'-ol
(8α, 9S)-(+)-9-AMino-cinchonan-6'-ol, Min. 90% | [Molecular Formula]
C19H23N3O | [MDL Number]
MFCD27978392 | [MOL File]
960050-59-3.mol | [Molecular Weight]
309.41 |
| Chemical Properties | Back Directory | [alpha ]
+107.9° (c 1.0, CHCl3) | [Boiling point ]
501.7±45.0 °C(Predicted) | [density ]
1.24±0.1 g/cm3(Predicted) | [form ]
Powder | [pka]
8.92±0.40(Predicted) | [color ]
off-white to pale brown | [Stability:]
store cold |
| Questions And Answer | Back Directory | [Reaction]
1. [2+3]-dipolar cycloaddition of cyclic enones.
2. Activation of α,β-unsaturated carbonyl compounds:
a) vinylogous α-ketol rearrangement.
b) vinylogous Michael addition of β-substituted α,β-unsaturated cyclohexanones.
3. Michael addition
a) α-nitroacetate to α,β-unsaturated ketones.
b) Diastereodivergent Michael addition to α-substituted, α,β-unsaturated ketones.
4. α-benzoyloxylation of α-branched aldehydes.
5. [4+2]-cycloadditions of β-substituted α,β-unsaturated cyclohexanones with polyconjugated malonitriles.
6. Vinylogous organocascade catalysis with control of remote stereochemistry in the synthesis of spirocyclic oxindoles.
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