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97739-46-3

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97739-46-3 Structure

97739-46-3 Structure
IdentificationBack Directory
[Name]

meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane
[CAS]

97739-46-3
[Synonyms]

meCgPPh
1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamante
1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane
1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane
1,3,5,7-TetraMethyl-6-phenyl-2,4,8-trioxa-6-phosphaadaMantane 97%
1,3,5,7-TetraMethyl-6-phenyl-2,4,8-trioxa-6-phosphaadaMantane,99%
1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane, 99%
1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane, (MeCgPPh)
1,3,5,7-TetraMethyl-8-phenyl-2,4,6-trioxa-8-phosphaadaMantane, 99% MeCgPPh
1,3,5,7-TetraMethyl-2,4,8-trioxa-6-phenyl-6-phosphaadaMantane, 98% (MeCgPPh)
meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane
[Molecular Formula]

C16H21O3P
[MDL Number]

MFCD10567051
[MOL File]

97739-46-3.mol
[Molecular Weight]

292.31
Chemical PropertiesBack Directory
[Melting point ]

106-111 °C
[Boiling point ]

363.4±42.0 °C(Predicted)
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

Powder
[color ]

white
[Sensitive ]

air sensitive, moisture sensitive
[InChI]

InChI=1S/C16H21O3P/c1-13-10-15(3)19-14(2,17-13)11-16(4,18-13)20(15)12-8-6-5-7-9-12/h5-9H,10-11H2,1-4H3
[InChIKey]

AVVSJWUWBATQBX-UHFFFAOYSA-N
[SMILES]

C12(C)CC3(C)OC(C)(CC(C)(O3)O1)P2C1=CC=CC=C1
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-37
[WGK Germany ]

3
[TSCA ]

No
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Uses]

A bulky, robust, and electron-poor ligand that gives efficient rhodium hydroformylation and palladium cross-coupling catalysts.
Spectrum DetailBack Directory
[Spectrum Detail]

meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane(97739-46-3)1HNMR
meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane(97739-46-3)31PNMR
Hazard InformationBack Directory
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings
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