ChemicalBook--->CAS DataBase List--->99438-28-5

99438-28-5

99438-28-5 Structure

99438-28-5 Structure
IdentificationBack Directory
[Name]

(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE
[CAS]

99438-28-5
[Synonyms]

(+)-B-methoxydiisocamphenylborane
(+)-B-methoxydiisocamphenylborane
(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE
(+)-B-Methoxydiisopinocampheylborane
(-)-DIISOPINOCAMPHEYLMETHOXYBORANE HYDRATE
(+)-B-methoxydiisopinocampheylborane hydrate
(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE HYDRATE
(-)-beta-Methoxydiisopinocampheylboranehydrate
cis-1,2,3,4-Tetrahydro-2-phenyl-1-naphthaleneaceticaci
(+)-B-Methoxydiisopinocampheylborane,(+)-Diisopinocampheylmethoxyborane
Methoxybis((1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)borane
Borinic acid, B,B-bis[(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]-, methyl ester
[Molecular Formula]

C21H37BO
[MDL Number]

MFCD21332906
[MOL File]

99438-28-5.mol
[Molecular Weight]

316.33
Chemical PropertiesBack Directory
[Boiling point ]

365.6±9.0 °C(Predicted)
[density ]

0.95±0.1 g/cm3(Predicted)
[Fp ]

>230 °F
[storage temp. ]

2-8°C
[BRN ]

6370228
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[F ]

10-21
Hazard InformationBack Directory
[Uses]

(-)-B-Methoxydiisopinocampheylborane hydrate is an intermediate used in the synthesis of homoallylic alcohol''s and several complex natural products.
[Uses]

(+)?-?B-?Methoxydiisopinocamp?heylborane is a chiral catalyst used in synthetic organic chemistry such as the bacterial macrolide glycoside (-?)?-?Lyngbyaloside B which maintains antiproliferative activity.
[Uses]

Reactant involved in:
  • Oxidative cyclization and alkylation for synthesis of ionomycin
  • Intramolecular conjugate addition for tetrahydropyran synthesis
  • Aldol addition and Suzuki coupling reactions
  • Allylation
  • Synthesis of alkanols
Spectrum DetailBack Directory
[Spectrum Detail]

(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE(99438-28-5)IR
(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE(99438-28-5)Raman
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