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996-70-3

996-70-3 Structure

996-70-3 Structure
IdentificationBack Directory
[Name]

TETRAKIS(DIMETHYLAMINO)ETHYLENE
[CAS]

996-70-3
[Synonyms]

TDAE
LABOTEST-BB LT00455105
octamethyl-ethenetetramin
OCTAMETHYL-ETHYLENETETRAMINE
Ethenetetramine, octamethyl-
Tetrakis(dimethylamino)ethene
tetrakis(diethylamino)ethylene
TETRAKIS(DIMETHYLAMINO)ETHYLENE
Octamethylethylenetetramine, TDAE
1,1,2,2-Tetra(dimethylamino)ethene
Tetrakis(dimethylamino)ethylene,98%
Tetrakis(dimethylamino)ethylene,97%
N,N',N'',N'''-tetramethylethylenediylidenetetraamine
N1,N1,N'1,N'1,N2,N2,N'2,N'2-octaMethylethene-1,1,2,2-tetraaMine
N,N,N',N',N'',N'',N''',N'''-Octamethylethene-1,1,2,2-tetraamine
N,N,N',N',N'',N'',N''',N'''-Octamethyl-1,1,2,2-ethenetetraamine
N,N,N',N',N'',N'',N''',N'''-Octamethyl-ethene-1,1,2,2-tetraamine
N,N,N',N',N'',N'',N''',N'''-Octamethyl-1,1,2,2-ethenetetrakisamine
[EINECS(EC#)]

213-638-1
[Molecular Formula]

C10H24N4
[MDL Number]

MFCD00009601
[MOL File]

996-70-3.mol
[Molecular Weight]

200.32
Chemical PropertiesBack Directory
[Appearance]

light yellow-green liquid with an unpleasant
[Melting point ]

>200 °C (decomp)
[Boiling point ]

98°C 25mm
[density ]

0.861 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.48(lit.)
[Fp ]

53°C
[storage temp. ]

0-10°C
[form ]

clear liquid
[pka]

6.47±0.70(Predicted)
[color ]

Light yellow to Yellow to Orange
[Stability:]

Stable. Incompatible with acid chlorides, acids, strong oxidizing agents, acid anhydrides, carbon dioxide, oxygen, chlorinated solvents. Reacts with oxygen in air to give a greenish-yellow emission. Flammable.
[BRN ]

1705900
[CAS DataBase Reference]

996-70-3
[NIST Chemistry Reference]

Tetrakis(dimethylamino)ethylene(996-70-3)
[EPA Substance Registry System]

Ethenetetramine, octamethyl-(996-70-3)
Hazard InformationBack Directory
[Chemical Properties]

light yellow-green liquid with an unpleasant
[Uses]

Involved in TDAE methodology for coupling and intramolecular Buchwald reactions

Acts as a reducing agent

Reactant involved in:
  • Dioxygenation
  • Insertion of aluminum anion into the C-N bond
  • Chemiluminescent reactions with oxygen
[reaction suitability]

reaction type: C-C Bond Formation
[Purification Methods]

Impurities include tetramethylurea, dimethylamine, tetramethylethanediamine and tetramethyloxamide. It is washed with water while being flushed with nitrogen to remove dimethylamine, dried over molecular sieves, then passed through a silica gel column (previously activated at 400o) under nitrogen. De-gas it in a vacuum line by distillation from a trap at 50o to one at -70o. Finally, it is stirred over sodium-potassium alloy for several days. [Holroyd et al. J Phys Chem 89 4244 1985, Wiberg Angew Chem Int Ed Engl 7 766 1968, Beilstein 4 IV 167.]
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

10-34
[Safety Statements ]

16-27-36/37/39-45-26
[RIDADR ]

3286
[WGK Germany ]

3
[TSCA ]

TSCA listed
[HS Code ]

2921.29.0055
[HazardClass ]

3.2
[PackingGroup ]

III
Spectrum DetailBack Directory
[Spectrum Detail]

TETRAKIS(DIMETHYLAMINO)ETHYLENE(996-70-3)IR1
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