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99604-67-8

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99604-67-8 Structure

99604-67-8 Structure
IdentificationBack Directory
[Name]

TRIS(ACETONITRILE)PENTAMETHYLCYCLOPENTADIENYLRUTHENIUM (I) HEXAFLUOROPHOSPHATE
[CAS]

99604-67-8
[Synonyms]

[RuCp*(MeCN)3]PF6
Tris(acetonitrile)pentamethylcyclopentadienylruthenium(II)
PentaMethylcyclopentadienyltris (acetonitrile)rutheniuM(II)
TRIS(ACETONITRILE)PENTAMETHYLCYCLOPENTADIENYLRUTHENIUM (I) HEXAFLUOROPHOSPHATE
TRIS-(ACETONITRILE)PENTAMETHYLCYCLOPENTADIENYLRUTHENIUM(II) HEXAFLUOROPHOSPHATE
Tris(acetonitrile)(eta5-pentamethylcyclopentadienyl)ruthenium hexafluorophosphate
Tris(acetonitrile)pentamethylcyclopentadienylruthenium(i)hexafluorophosphate,min.
Tris(acetonitrile)pentaMethylcyclopentadienylrutheniuM(II) hexafluorophosphate,98%
Tris(acetonitrile)pentamethylcyclopentadienylruthenium(II)hexafluorophosphate,min.98%
Tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate, min. 98%
[Molecular Formula]

C16H24F6N3PRu 5*
[MDL Number]

MFCD04117715
[MOL File]

99604-67-8.mol
[Molecular Weight]

504.42
Chemical PropertiesBack Directory
[storage temp. ]

2-8°C
[form ]

Powder
[color ]

yellow orange
[Sensitive ]

air sensitive, store cold
[InChI]

1S/C10H16.3C2H3N.F6P.Ru/c1-6-7(2)9(4)10(5)8(6)3;3*1-2-3;1-7(2,3,4,5)6;/h6H,1-5H3;3*1H3;;/q;;;;-1;+1
[InChIKey]

IYEMDYLFXFMECZ-UHFFFAOYSA-N
[SMILES]

[Ru+].CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F.CC1C(C)=C(C)C(C)=C1C
[CAS DataBase Reference]

99604-67-8
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Questions And AnswerBack Directory
[Reactions]

  • Useful catalyst for the hydrosilylation of internal and terminal alkynes. The reaction has also been extended to intramolecular hydrosilylation.
  • Catalyst for the cycloisomerization of diynes.
  • Catalyst for synthesis of furans from bis(alkynes) and DMSO.
Reactions of 99604-67-8
Hazard InformationBack Directory
[Uses]

Hydrosilylation Catalysts
[reaction suitability]

core: ruthenium
reagent type: catalyst
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