| Identification | Back Directory | [Name]
CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) | [CAS]
99897-61-7 | [Synonyms]
C9H7RuCl2(C18H15P)
Reaxys ID: 11961247
CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)R&
Chloro-(indenyl)-bis-(triphenylphosphino)-ruthenium
CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
Ruthenium,chloro[(1,2,3,3a,7a-h)-1H-inden-1-yl]bis(triphenylphosphine)-
Chloro(indenyl)bis(triphenylphosphine)rutheniuM(II),dichloroMethane adduct,98%
CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II),DICHLOROMETHANEADDUCT,MIN.
Chloro(indenyl)bis(triphenylphosphine)ruthenium(II),dichloromethaneadduct,min.98%
Chloro(indenyl)bis(triphenylphosphine)ruthenium(II) may contain <=1 molar equivalent dichloromethane/acetone | [Molecular Formula]
C45H37ClP2Ru5* | [MDL Number]
MFCD01073793 | [MOL File]
99897-61-7.mol | [Molecular Weight]
776.25 |
| Chemical Properties | Back Directory | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
crystal | [color ]
red-brown | [InChI]
1S/2C18H15P.C9H7.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-5-9-7-3-6-8(9)4-1;;/h2*1-15H;1-7H;1H;/q;;;;+1/p-1 | [InChIKey]
AUSVTIHCDLKYHV-UHFFFAOYSA-M | [SMILES]
Cl[Ru].[CH]1[CH][C]2C=CC=C[C]2[CH]1.c3ccc(cc3)P(c4ccccc4)c5ccccc5.c6ccc(cc6)P(c7ccccc7)c8ccccc8 |
| Hazard Information | Back Directory | [Uses]
Catalyst for:
- Single-chain folding of polymers
- Domino redox bicycloisomerization
- Selective radical addition with a designed heterobifunctional halide
- Tandem living radical polymerization via in situ monomer transformation with alcohols
- Atom-economical synthesis of nitrogen heterocycles
Reactant for the synthesis of chiral-at-metal ruthenium allenylidene complexes | [reaction suitability]
core: ruthenium
reagent type: catalyst |
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