959395-10-9
中文名称
(2S,2'S) - ( - ) - [N,N'-双(2 - 吡啶基甲基]-2,2' - 联吡咯烷双(乙腈)铁(II)六氟锑酸盐
CAS
959395-10-9
分子式
C24H32F12FeN6Sb2
959395-10-9 结构式
基本信息
中文别名
WHITE-CHEN 催化剂(2S,2′S-(-)-[N,N′-双(2-吡啶基甲基)]-2,2′-二吡咯烷双(乙腈)六氟锑酸铁(II)
(2S,2'S) - ( - ) - [N,N'-双(2 - 吡啶基甲基]-2,2' - 联吡咯烷双(乙腈)铁(II)六氟锑酸盐
(S,S-(2-({(S)-2-[(S)-1-(吡啶-2-基甲基)吡咯烷-2-基]吡咯烷-1-基}甲基)吡啶)(双-乙腈)六氟锑酸铁(II)
英文别名
Fe(R,R-PDP)Fe(S,S-PDP)
White-Chen catalyst
[Fe(S,S-PDP)(CH3CN)2](SbF6)2
[Fe(R,R-PDP)(CH3CN)2](SbF6)2
(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
(2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
acetonitrile:hexafluoroantimony(1-):iron(2+):2-[[(2R)-2-[(2R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl]methyl]pyridine
(2S,2'S)-(-)-[N,N'-Bis(2-pyridylmethyl]-2,2'-bipyrrolidinebis(acetonitrile) iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst
Iron(II) (R,R-(2-({(R)-2-[(R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate
物理化学性质
熔点215-226 °C
形态粉末
颜色purple
旋光性 (optical activity)[α]20/D 30.0 to 20.0°, c = 0.2 in acetonitrile
敏感性空气敏感
CAS 数据库959395-10-9
