17β,23β-Epoxyveratraman-3β,11β-diol

17β,23β-Epoxyveratraman-3β,11β-diol Struktur
20226-97-5
CAS-Nr.
20226-97-5
Englisch Name:
17β,23β-Epoxyveratraman-3β,11β-diol
Synonyma:
Veratrobasine;17β,23β-Epoxyveratraman-3β,11β-diol;Spiro[9H-benzo[a]fluorene-9,2'(3'H)-furo[3,2-b]pyridine]-3,11-diol, 1,2,3,3'a,4,4',5',6,6',6a,6b,7,7',7'a,8,11,11a,11b-octadecahydro-3',6',10,11b-tetramethyl-, (2'R,3S,3'R,3'aS,6'S,6aS,6bS,7'aR,11R,11aS,11bR)-
CBNumber:
CB02341349
Summenformel:
C27H41NO3
Molgewicht:
427.62
MOL-Datei:
20226-97-5.mol

17β,23β-Epoxyveratraman-3β,11β-diol Eigenschaften

Schmelzpunkt:
285-8°C

Sicherheit

17β,23β-Epoxyveratraman-3β,11β-diol Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

A steroidal alkaloid of Veratrum album, the base crystallizes as colourless prisms. It has [α]20D - 126° (c 0.65, pyridine) and - 76.6° (c 0.58, EtOH). The sulphate yields colourless crystals from aqueous EtOH, m.p. 250-3°C (dec.); [α]20D° - 175° (c 0.22, 75% EtOH) and the acetyl derivative forms prisms from Me2CO with one mole of solvent. The structure has been confirmed by the total synthesis of the alkaloid.

Einzelnachweise

Kutney et al., Intrasci. Chem. Rep., 4, 265 (1970)

17β,23β-Epoxyveratraman-3β,11β-diol Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


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  • 17β,23β-Epoxyveratraman-3β,11β-diol
  • Veratrobasine
  • Spiro[9H-benzo[a]fluorene-9,2'(3'H)-furo[3,2-b]pyridine]-3,11-diol, 1,2,3,3'a,4,4',5',6,6',6a,6b,7,7',7'a,8,11,11a,11b-octadecahydro-3',6',10,11b-tetramethyl-, (2'R,3S,3'R,3'aS,6'S,6aS,6bS,7'aR,11R,11aS,11bR)-
  • 20226-97-5
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