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Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos]

Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos]　 Struktur
944450-50-4
CAS-Nr.
944450-50-4
Englisch Name:
Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos]　
Synonyma:
RU(OAC)2[(S)-DM-SEGPHOS;(S)-Ru(OAc)2(DM-SEGPHOS);Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II);Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(;Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dm-segphos];Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dm-segphos(R)]
CBNumber:
CB02512471
Summenformel:
C50H52O8P2Ru
Molgewicht:
943.98
MOL-Datei:
944450-50-4.mol
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Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos] Eigenschaften

Schmelzpunkt:
>100°C
storage temp. 
2-8°C
Aggregatzustand
solid
Farbe
yellow to brownish-red to dark green
Sensitive 
air sensitive
CAS Datenbank
944450-50-4

Sicherheit

WGK Germany  3

Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos] Chemische Eigenschaften,Einsatz,Produktion Methoden

Verwenden

(S)-Ru(OAc)2(DM-SEGPHOS?) can be used as a catalyst in:
  • The enantioselective asymmetric hydrogenation reaction.
  • The asymmetric reductive amination reaction.
  • The total synthesis of (-)-tubingensin B via Suzuki-Miyaura coupling and aryne cyclization reactions.

Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos] Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos] Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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  • Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dm-segphos]
  • (S)-Ru(OAc)2(DM-SEGPHOS)
  • Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dm-segphos(R)]
  • Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(
  • RU(OAC)2[(S)-DM-SEGPHOS
  • Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II)
  • 944450-50-4
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