SPhos Pd G2

SPhos Pd G2 Struktur
1375325-64-6
CAS-Nr.
1375325-64-6
Englisch Name:
SPhos Pd G2
Synonyma:
RK1001022;SPhos Pd G2;SPhos Pd G2 catalyst;SPhos Palladacycle Gen.2;SPhos Pd G2 ISO 9001:2015 REACH;2nd Generation SPhos Precatalyst;Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl...;chloropalladium(1+),dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphane,2-phenylaniline;Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II);Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)
CBNumber:
CB52686111
Summenformel:
C38H45ClNO2PPd
Molgewicht:
720.63
MOL-Datei:
1375325-64-6.mol

SPhos Pd G2 Eigenschaften

Schmelzpunkt:
218°C (dec.)
Aggregatzustand
Powder
Farbe
white
InChIKey
PYMQIHHZINPLDV-UHFFFAOYSA-N
SMILES
P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1OC)OC)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-]

Sicherheit

WGK Germany  3

SPhos Pd G2 Chemische Eigenschaften,Einsatz,Produktion Methoden

Verwenden

Application in Suzuki-Miyaura coupling:
  • Self-arylation of 1-alkyl-3-bromo-2-phenyl-2,1-borazaronaphthalenes to form 2,1-borazaronaphthols.
  • Suzuki–Miyaura coupling of [Ru(bpy)2]+ with 4-carboxyphenylboronic acid.
  • Suzuki–Miyaura coupling of β-borylated porphyrins with 2-iodoaniline.

Allgemeine Beschreibung

SPhos Pd G2 is a second generation (G2) precatalyst in which phenethylamine based backbone of the (G1) complex is substituted with a biphenyl-based ligand. This improvement on the previous generation allows creating the active palladium species at room temperature with weak phosphate or carbonate bases. The catalyst proves remarkably adept at achieving a variety of Suzuki-Miyaura couplings among other cross-coupling reactions.

SPhos Pd G2 Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


SPhos Pd G2 Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • CHLORO(2-DICYCLOHEXYLPHOSPHINO-2',6'-DIMETHOXY-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)MIN.98%[SPHOSPALLADACYCLEGEN.2]
  • SPhos Pd G2
  • 2nd Generation SPhos Precatalyst
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)
  • Chloro(2-dicyclohexylphosphino-2',6'-diMethoxy-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl) palladiuM(II), Min. 98% [SPhos Palladacycle]
  • SPhos Palladacycle Gen.2
  • SPhos Pd G2 catalyst
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / SPhos Pd G2
  • SPhos Pd G2 ISO 9001:2015 REACH
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl...
  • SPhos Pd G2 / Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • chloropalladium(1+),dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphane,2-phenylaniline
  • RK1001022
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II) (SPhos Pd G2)
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II) min.
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II)
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)
  • 1375325-64-6
  • C38H45ClNO2PPd
  • C26H35O2PC12H10ClNPd
  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series
  • Pd
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