(8S)-8α,13β-Dihydroxyserratinane-5-one

(8S)-8α,13β-Dihydroxyserratinane-5-one Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

A further alkaloid present in Lycopodium serratum Thunb. vaT. thunbergii Mak. The base crystallizes from Me₂CO in colourless prisms and has [α]⁸_D - 27.8° (c 1.44, EtOH). Two non-phenolic hydroxyl groups are present and the alkaloid forms the 8-0-acetate, m.p. 244-5°C; the l3-0-acetate, m.p. 240-2°C and the di-O-acetate, m.p. 1 57-8°C. The tetracyc1ic structure has been proposed on the basis of the mass spectra of the alkaloid and a tentative biogenesis from lycodoline-type alkaloids also proposed.

Einzelnachweise

Inubushi et al., Tetrahedron Lett., 1537 (1966)
Mass spectra:
Inubishietal., Tetrahedron, 24,3541 (1968)
Stereochemistry :
Inubushi et al., Tetrahedron Lett., 1551 (1966)
Biosythesis:
Inubushi et aI., Chem. Pharm. Bull. (Tokyo), 16,92 (1968)

(8S)-8α,13β-Dihydroxyserratinane-5-one Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

(8S)-8α,13β-Dihydroxyserratinane-5-one Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Firmenname	Telefon	E-Mail	Land	Produktkatalog	Edge Rate
TargetMol Chemicals Inc.	+1-781-999-5354	support@targetmol.com	United States	19973	58

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• (13S)-8α,13-Dihydroxyserratinan-5-one
• (8S)-8α,13β-Dihydroxyserratinane-5-one
• Serratinine
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• 5H,9H,12H-Indeno[7a,1-h]indolizin-12-one, decahydro-1,4-dihydroxy-2-methyl-, (1S,2S,4S,4aS,11aR,13aS)- (9CI)
• 5545-99-3