C10603
- CAS No.
- 24185-51-1
- Chemical Name:
- C10603
- Synonyms
- C10603;Lunarine;(1E,15E,20aR,24aS)-4,5,6,7,8,9,10,11,12,13,20a,21,23,24-Tetradecahydro-17,19-etheno-22H-benzofuro[3a,3-n][1,5,10]triazacycloicosine-3,14,22-trione;17,19-Etheno-22H-benzofuro[3a,3-n][1,5,10]triazacycloeicosine-3,14,22-trione, 4,5,6,7,8,9,10,11,12,13,20a,21,23,24-tetradecahydro-, (1E,15E,20aR,24aS)-
- CBNumber:
- CB01246395
- Molecular Formula:
- C25H31N3O4
- Molecular Weight:
- 437.54
- MDL Number:
- MOL File:
- 24185-51-1.mol
C10603 Chemical Properties,Uses,Production
Description
A major alkaloid of the seeds of Lunaria biennis Mnch. and also found in L. rediviva, this alkaloid crystallizes as colourless needles from aqueous Me2CO. It is dextrorotatory with [α]27D + 300° (CHCI3) and forms crystalline salts including the hydrochloride, m.p. above 340°C; hydrobromide, m.p. 280-340°C, aurichloride, m.p. 166-170°C (dec.) and the sulphate, m.p. above 340°C.
References
Steinegger, Reichstein., Pharrn. Acta Helv., 22, 258 (1947)
Boit., Chern. Ber., 87,1082 (1954)
Janot, LeMen., Bull. Soc. Chirn. Fr., 1840 (1956)
Poiter et al., ibid, 456 (1959)
Bladonetal., Tetrahedron Lett., No.9, 18(1959)
Poiter et al., Tetrahedron Lett., No. 18,36 (1960)
Huneck., Naturwiss., 49, 233 (1962)
Poiter et al., Tetrahedron Lett., 293 (1963)
Crystal structure:
Tamura et al., Chern. Cornrnun., 485 (1965)
C10603 Preparation Products And Raw materials
Raw materials
Preparation Products
C10603 Suppliers
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