(20ξ,25ξ)-23,26-Epoxy-3β-hydroxy-16,28-seco-5α-solanid-22(28)-en-6-one

(20ξ,25ξ)-23,26-Epoxy-3β-hydroxy-16,28-seco-5α-solanid-22(28)-en-6-one structure

CAS No.: 27336-00-1

Chemical Name:: (20ξ,25ξ)-23,26-Epoxy-3β-hydroxy-16,28-seco-5α-solanid-22(28)-en-6-one

Synonyms: Korsevinine;(20ξ,25ξ)-23,26-Epoxy-3β-hydroxy-16,28-seco-5α-solanid-22(28)-en-6-one;(20Ξ,23Ξ,25Ξ,26Ξ)-23,26-epoxy-3β-hydroxy-(5α)-16,28-seco-solanid-22(28)-en-6-one;Pregnan-6-one, 3-hydroxy-20-(6-methyl-7-oxa-2-azabicyclo[2.2.1]hept-2-en-3-yl)-, (3β,5α)- (9CI)

CBNumber:: CB22213899

Molecular Formula:: C27H41NO3

Molecular Weight:: 427.63

MDL Number:

MOL File:: 27336-00-1.mol

Request For Quotation

(20ξ,25ξ)-23,26-Epoxy-3β-hydroxy-16,28-seco-5α-solanid-22(28)-en-6-one Properties

Melting point	224-5°C
Boiling point	553.2±45.0 °C(Predicted)
Density	1.38±0.1 g/cm3(Predicted)
pka	14.89±0.70(Predicted)

(20ξ,25ξ)-23,26-Epoxy-3β-hydroxy-16,28-seco-5α-solanid-22(28)-en-6-one Chemical Properties,Uses,Production

Description

A further base isolated from the bulbs of Korolkowia sewerzowii, this alkaloid forms colourless crystals from Me2CO and has [α]_D - 16.04°. The O-acetate is crystalline with m.p. 154-5°C.

References

Nuriddinov, Yunusov., Khim. Prir. Soedin., S, 600 (1969)

(20ξ,25ξ)-23,26-Epoxy-3β-hydroxy-16,28-seco-5α-solanid-22(28)-en-6-one Preparation Products And Raw materials

Raw materials

Preparation Products

(20ξ,25ξ)-23,26-Epoxy-3β-hydroxy-16,28-seco-5α-solanid-22(28)-en-6-one Korsevinine (20Ξ,23Ξ,25Ξ,26Ξ)-23,26-epoxy-3β-hydroxy-(5α)-16,28-seco-solanid-22(28)-en-6-one Pregnan-6-one, 3-hydroxy-20-(6-methyl-7-oxa-2-azabicyclo[2.2.1]hept-2-en-3-yl)-, (3β,5α)- (9CI) 27336-00-1