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3-Bromopropyne

3-Bromopropyne
3-Bromopropyne structure
CAS No.
106-96-7
Chemical Name:
3-Bromopropyne
Synonyms
PBR;propargyl;Dow S-1925;3-Bromopropine;3-BROMOPROPYNE;3-bromo-propyn;-Bromo-propyne;3-bromoallylene;Propargylbromid;G-BROMOALLYLENE
CBNumber:
CB3162370
Molecular Formula:
C3H3Br
Formula Weight:
118.96
MOL File:
106-96-7.mol

3-Bromopropyne Properties

Melting point:
-61°C
Boiling point:
97 °C
Density 
1.38 g/mL at 20 °C
refractive index 
n20/D 1.494
Flash point:
65 °F
storage temp. 
Refrigerator
form 
Powder
color 
White to off-white
Water Solubility 
Miscible with ethanol, ether, benzene, carbon tetrachloride and chloroform. Immiscible with water.
Sensitive 
Light Sensitive
BRN 
605309
InChIKey
YORCIIVHUBAYBQ-UHFFFAOYSA-N
CAS DataBase Reference
106-96-7(CAS DataBase Reference)
NIST Chemistry Reference
1-Propyne, 3-bromo-(106-96-7)
EPA Substance Registry System
1-Propyne, 3-bromo-(106-96-7)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  F,T,C
Risk Statements  60-61-20/21-25-63-36/37/38-11-67-65-48/20
Safety Statements  53-16-36/37/39-45-37/39-28A-26-62-36/37
RIDADR  UN 2345 3/PG 2
WGK Germany  3
RTECS  UK4375000
8
Hazard Note  Highly Flammable/Toxic/Corrosive
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29033990
Hazardous Substances Data 106-96-7(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H333 May be harmful if inhaled Acute toxicity,inhalation Category 5 P304+P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H361 Suspected of damaging fertility or the unborn child Reproductive toxicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P331 Do NOT induce vomiting.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P403+P235 Store in a well-ventilated place. Keep cool.

NFPA 704

Diamond Hazard Value Description
3
3 4
Health   3 Short exposure could cause serious temporary or moderate residual injury (e.g. liquid hydrogen, sulfuric acid, calcium hypochlorite, hexafluorosilicic acid)
Flammability   3 Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions . Liquids having a flash point below 22.8 °C (73 °F) and having a boiling point at or above 37.8 °C (100 °F) or having a flash point between 22.8 and 37.8 °C (73 and 100 °F). (e.g. gasoline, acetone)
Instability   4 Readily capable of detonation or explosive decomposition at normal temperatures and pressures (e.g. nitroglycerin,chlorine dioxide, nitrogen triiodide)
Special  

(NFPA, 2010)

3-Bromopropyne price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 530409 Propargyl bromide solution 80 wt. % in xylene 106-96-7 50g $77.3 2018-11-13 Buy
Sigma-Aldrich 530409 Propargyl bromide solution 80 wt. % in xylene 106-96-7 125g $167 2018-11-13 Buy
TCI Chemical P0484 Propargyl Bromide (stabilized with MgO) >97.0%(GC) 106-96-7 25g $44 2018-11-22 Buy
TCI Chemical P0484 Propargyl Bromide (stabilized with MgO) >97.0%(GC) 106-96-7 100g $133 2018-11-22 Buy
Alfa Aesar A16580 Propargyl bromide, 80% in toluene, stab. with MgO 106-96-7 50ml $77.2 2018-11-13 Buy

3-Bromopropyne Chemical Properties,Uses,Production

Chemical Properties

yellow solution

Uses

Used to make propargylic amines employed in enyne metathesis.1Employed in the propargylation of spiro ketones,2 allylic alcohols,3 and enone complexes.4

General Description

A colorless to light yellow liquid substance with a sharp odor. Flash point 65°F. Denser than water and insoluble in water. Vapors are heavier than air. May be irritating to skin and eyes. Used to make other chemicals. 3-Bromopropyne may decompose explosively with mild shock.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

3-Bromopropyne is soluble in alcohol, ether, chloroform, carbon tetrachloride and carbon disulfide. 3-Bromopropyne is highly flammable and a dangerous fire risk, sensitive to shock. 3-Bromopropyne is used in organic syntheses, preparation of resins and perfume intermediates [Hawley]. There is a high danger of formation of explosive metal acetylides, when 3-Bromopropyne comes in contact with copper, high-copper alloys, mercury, or silver.

Hazard

Flammable, dangerous fire and explosion risk. Irritant.

Health Hazard

3-Bromopropyne is very toxic via the oral route. If inhaled, may be harmful; contact may cause burns to skin and eyes.

Fire Hazard

3-Bromopropyne detonates at 428F or more; ignites by impact. Emits highly toxic fumes of bromides when heated to decomposition. Reacts vigorously with oxidizing materials. Becomes shock-sensitive when mixed with chloropicrin. Unstable, avoid heat, flame, shock, and other chemicals

Safety Profile

A poison by ingestion. A dangerous fire hazard when exposed to heat or flame. The aerated liquid may be ignited by pressure. A dangerous, extremely shock-sensitive explosive. It can detonate when heated to 22O°C, by impact (especially when mixed with chloropicrin), or when heated whde confined. May explode on contact with copper, high copper alloys, mercury, or silver. Mixtures with trichloronitromethane are shockand heat- sensitive explosives. Can react vigorously with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits highly toxic fumes of Br-. See also ACETYLENE COMPOUNDS and BROMIDES.

3-Bromopropyne Preparation Products And Raw materials

Raw materials

Preparation Products


3-Bromopropyne Suppliers

Global( 238)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
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3-Bromopropyne Spectrum


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