Acetylthiomethyl-diphenylphosphine borane complex

CAS No.
446822-71-5
Chemical Name:
Acetylthiomethyl-diphenylphosphine borane complex
Synonyms
Acetylthiomethyl-diphenylphosphine borane complex;Acetylthiomethyl-diphenylphosphine borane complex >=98.0%
CBNumber:
CB42090207
Molecular Formula:
C15H18BOPS
Molecular Weight:
288.157
MDL Number:
MOL File:
446822-71-5.mol
Last updated:2022-08-15 17:37:31

Acetylthiomethyl-diphenylphosphine borane complex Properties

Melting point 52-55 °C
storage temp. 2-8°C

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  3

Acetylthiomethyl-diphenylphosphine borane complex price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 670359 Acetylthiomethyl-diphenylphosphine borane complex ≥98.0% 446822-71-5 250mg $180 2022-05-15 Buy
Sigma-Aldrich 670359 Acetylthiomethyl-diphenylphosphine borane complex ≥98.0% 446822-71-5 1g $716 2022-05-15 Buy
American Custom Chemicals Corporation BOR0003689 ACETYLTHIOMETHYL-DIPHENYLPHOSPHINE BORANE COMPLEX 95.00% 446822-71-5 5MG $496.09 2021-12-16 Buy
Product number Packaging Price Buy
670359 250mg $180 Buy
670359 1g $716 Buy
BOR0003689 5MG $496.09 Buy

Acetylthiomethyl-diphenylphosphine borane complex Chemical Properties,Uses,Production

Uses

  • Traceless Staudinger ligation reagent with borane protecting group.
  • The borane group stabilizes the phosphine against oxidation and can be easily removed with mild basic or acidic conditions to yield the active phosphine.
  • After reaction with an azide, the phosphine is eliminated in the presence of water to yield a native amide bond.
  • Used in the synthesis of cyclic peptides.

Uses

Traceless Staudinger ligation reagent with borane protecting group. The borane group stabilizes the phosphine against oxidation and can be easily removed with mild basic or acidic conditions to yield the active phosphine. After reaction with an azide, the phosphine is eliminated in the presence of water to yield a native amide bond. Used in the synthesis of cyclic peptides.

Acetylthiomethyl-diphenylphosphine borane complex Preparation Products And Raw materials

Raw materials

Preparation Products

Acetylthiomethyl-diphenylphosphine borane complex Suppliers

Global( 6)Suppliers
Supplier Tel Email Country ProdList Advantage
Alfa Chemistry
+1-5166625404 Info@alfa-chemistry.com United States 21317 58
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696; info@hanhongsci.com China 42982 64
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Energy Chemical 021-58432009 400-005-6266 marketing@energy-chemical.com China 44941 58
Acetylthiomethyl-diphenylphosphine borane complex Acetylthiomethyl-diphenylphosphine borane complex >=98.0% 446822-71-5 C15H18BOPS Catalysis and Inorganic Chemistry Chemical Synthesis Chemical Ligation Other LigandsSpecialty Synthesis Staudinger Ligation