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(R)-N-((3-Methylpyridin-2-yl)methyl)-7′-di(3,5-di-tert-butylphenyl)phosphino-1,1′-spirobiindanyl-7-amine

(R)-N-((3-Methylpyridin-2-yl)methyl)-7′-di(3,5-di-tert-butylphenyl)phosphino-1,1′-spirobiindanyl-7-amine structure

CAS No.: 1298133-36-4

Chemical Name:: (R)-N-((3-Methylpyridin-2-yl)methyl)-7′-di(3,5-di-tert-butylphenyl)phosphino-1,1′-spirobiindanyl-7-amine

Synonyms: (R)-SpiroPAP-Me;(R)-SPIROPAP-3-ME;(R)-DTB-SpiroPAP-3-Me;99% ee) (R)-DTB-SpiroPAP-3-Me;(R)-N-((3-Methylpyridin-2-yl)methyl)-7′-di(3,5-di-tert-butylphenyl)phosphino-1,1′-spirobiindanyl-7-amine;(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7''-[(3-methylpyridine-2-ylmethyl)amino]-2,2'',3,3''-tetrahydro-1,1''-spirobiindane;N-[(1R)-7'-[BIS[3,5-BIS(TERT-BUTYL)PHENYL]PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDEN]-7-YL]-3-METHYL-2-PYRIDINEMETHANAMINE;(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 98% (>N-[(1R)-7'-[Bis[3,5-bis(tert-butyl)phenyl]phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-inden]-7-yl]-3-methyl-2-pyridinemethanamine,99%e.e.;2-Pyridinemethanamine, N-[(1R)-7'-[bis[3,5-bis(1,1-dimethylethyl)phenyl]phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-inden]-7-yl]-3-methyl-

CBNumber:: CB43044326

Molecular Formula:: C52H65N2P

Molecular Weight:: 749.06

MDL Number:: MFCD30187941

MOL File:: 1298133-36-4.mol

Last updated:2023-04-23 13:52:06

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(R)-N-((3-Methylpyridin-2-yl)methyl)-7′-di(3,5-di-tert-butylphenyl)phosphino-1,1′-spirobiindanyl-7-amine Properties

Melting point	160-161°C
alpha	+213 (c 0.5, CH2Cl2)
Boiling point	764.0±60.0 °C(Predicted)
pka	5.04±0.22(Predicted)
form	solid
color	off-white
Sensitive	air sensitive

(R)-N-((3-Methylpyridin-2-yl)methyl)-7′-di(3,5-di-tert-butylphenyl)phosphino-1,1′-spirobiindanyl-7-amine price More Price(3)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Strem Chemicals	15-5158	(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 98% (>99% ee) (R)-DTB-SpiroPAP-3-Me	1298133-36-4	25mg	$85	2024-03-01	Buy
Strem Chemicals	15-5158	(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 98% (>99% ee) (R)-DTB-SpiroPAP-3-Me	1298133-36-4	100mg	$250	2024-03-01	Buy
ChemScene	CS-0059977	(R)-DTB-SpiroPAP-3-Me	1298133-36-4	50mg	$240	2021-12-16	Buy

Product number	Packaging	Price	Buy
15-5158	25mg	$85	Buy
15-5158	100mg	$250	Buy
CS-0059977	50mg	$240	Buy

(R)-N-((3-Methylpyridin-2-yl)methyl)-7′-di(3,5-di-tert-butylphenyl)phosphino-1,1′-spirobiindanyl-7-amine Chemical Properties,Uses,Production

Reactions

Iridium/ligand catalyst for the highly efficient, asymmetric hydrogenation of β-aryl and β-ketoesters.
Extremely efficient chiral iridium catalyst used for the asymmetric hydrogenation of ketones.
Iridium/ligand catalyst for the highly efficient, asymmetric hydrogenation of β-aryl and β-ketoesters.

(R)-N-((3-Methylpyridin-2-yl)methyl)-7′-di(3,5-di-tert-butylphenyl)phosphino-1,1′-spirobiindanyl-7-amine Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-N-((3-Methylpyridin-2-yl)methyl)-7′-di(3,5-di-tert-butylphenyl)phosphino-1,1′-spirobiindanyl-7-amine Suppliers

Global( 23)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Arbor Chemical Co., Ltd.	021-60451682	act@arborchemical.com	CHINA	906	58
Zhuoer Chemical Co., Ltd	02120970332; +8613524231522	sales@zhuoerchem.com	China	3015	58
Labnetwork lnc.	+86-27-50766799 +8618062016861	contact@labnetwork.com	China	19994	58
Aladdin Scientific	+1-833-552-7181	sales@aladdinsci.com	United States	52927	58
Daicel Chiral Technologies (China)CO.,LTD	021-50460086-9 15921403865	han_yajun@dctc.daicel.com	China	6818	65
Shanghai Chiral bio-compound co., Ltd.	021-5068 3667/17749785980/1029026415; 17749785980	1029026415@qq.com	China	2790	58
LaaJoo	021-60702684 18516024827	huang.jiayi@sinocompound.com	China	2654	58
Greenherbs Science and Technology Development Co., Ltd.	010-61136123	pub02@greenherbs.com.cn	China	4049	58
3A Chemicals	400-668-9898	service@3achem.com	China	20569	58
Shanghai Anyinuo Biomedical Technology Co., Ltd.	021-88888888	420970979@qq.com	China	2806	58

Supplier	Advantage
Shanghai Arbor Chemical Co., Ltd.	58
Zhuoer Chemical Co., Ltd	58
Labnetwork lnc.	58
Aladdin Scientific	58
Daicel Chiral Technologies (China)CO.,LTD	65
Shanghai Chiral bio-compound co., Ltd.	58
LaaJoo	58
Greenherbs Science and Technology Development Co., Ltd.	58
3A Chemicals	58
Shanghai Anyinuo Biomedical Technology Co., Ltd.	58

(R)-N-((3-Methylpyridin-2-yl)methyl)-7′-di(3,5-di-tert-butylphenyl)phosphino-1,1′-spirobiindanyl-7-amine (R)-SPIROPAP-3-ME (R)-SpiroPAP-Me N-[(1R)-7'-[BIS[3,5-BIS(TERT-BUTYL)PHENYL]PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDEN]-7-YL]-3-METHYL-2-PYRIDINEMETHANAMINE (R)-DTB-SpiroPAP-3-Me N-[(1R)-7'-[Bis[3,5-bis(tert-butyl)phenyl]phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-inden]-7-yl]-3-methyl-2-pyridinemethanamine,99%e.e. (R)-(+)-7-BIS(3,5-DI-T-BUTYLPHENYL)PHOSPHINO-7'-[(3-METHYLPYRIDINE-2-YLMETHYL)AMINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE,MIN.98%(>99%EE)(R)-DTB-SPIROPAP-3-ME 2-Pyridinemethanamine, N-[(1R)-7'-[bis[3,5-bis(1,1-dimethylethyl)phenyl]phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-inden]-7-yl]-3-methyl- 99% ee) (R)-DTB-SpiroPAP-3-Me (R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 98% (> (R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7''-[(3-methylpyridine-2-ylmethyl)amino]-2,2'',3,3''-tetrahydro-1,1''-spirobiindane 1298133-36-4 C52H65N2P Chiral Phosphine Chiral Spiro Ligand