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1,2-Epoxy-4-vinylcyclohexane

1,2-Epoxy-4-vinylcyclohexane structure

CAS No.: 106-86-5

Chemical Name:: 1,2-Epoxy-4-vinylcyclohexane

Synonyms: EP-101;epoxide101;Epoxide 101;unoxatepoxide101;Unoxat epoxide 101;4-Vinylcyclohexene oxide;vinylcyclohexenemonoxide;3-Vinylcyclohexene oxide;4-Vinyl epoxycyclohexane;Vinylcyclohexene monoxide

CBNumber:: CB4410193

Molecular Formula:: C8H12O

Molecular Weight:: 124.18

MDL Number:: MFCD00022356

MOL File:: 106-86-5.mol

MSDS File:: SDS

Last updated:2026-01-13 11:20:04

Product description	Number	Pack Size	Price
4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers 98%	152544	250ml	$132
1,2-Epoxy-4-vinylcyclohexane (mixture of isomers) >98.0%(GC)	E0956	25mL	$27
1,2-Epoxy-4-vinylcyclohexane (mixture of isomers) >98.0%(GC)	E0956	250mL	$95
1,2-Epoxy-4-vinylcyclohexane	E892145	2.5mL	$45
4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers 98%	2309-1-01	100g	$45
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1,2-Epoxy-4-vinylcyclohexane Properties

Melting point	-100°C(lit.)
Boiling point	169 °C(lit.)
Density	0.952 g/mL at 25 °C(lit.)
refractive index	n20/D 1.469(lit.)
Flash point	115 °F
storage temp.	2-8°C
form	clear liquid
color	Colorless to Almost colorless
Specific Gravity	0.952
InChI	InChI=1S/C8H12O/c1-2-6-3-4-7-8(5-6)9-7/h2,6-8H,1,3-5H2
InChIKey	SLJFKNONPLNAPF-UHFFFAOYSA-N
SMILES	C12C(O1)CCC(C=C)C2
CAS DataBase Reference	106-86-5(CAS DataBase Reference)
EWG's Food Scores	1
NIST Chemistry Reference	7-Oxabicyclo[4.1.0]heptane, 3-ethenyl-(106-86-5)
EPA Substance Registry System	7-Oxabicyclo[4.1.0]heptane, 3-ethenyl- (106-86-5)
UNSPSC Code	12162002
NACRES	NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS02,GHS07,GHS08
Signal word	Warning
Hazard statements	H226-H302-H319-H351
Precautionary statements	P201-P210-P301+P312+P330-P305+P351+P338-P308+P313
PPE	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes	T,Xn
Risk Statements	45-10-20/21/22-40-36-22
Safety Statements	53-16-23-36/37/39-45-36/37-26
RIDADR	UN 3271 3/PG 3
WGK Germany	3
RTECS	RN8770000
TSCA	TSCA listed
HazardClass	3.2
PackingGroup	III
HS Code	29109000
Storage Class	3 - Flammable liquids
Hazard Classifications	Acute Tox. 4 Oral Carc. 2 Eye Irrit. 2 Flam. Liq. 3
Limited Quantities	5.0 L (1.3 gallons) (liquid)
Excepted Quantities	Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

1,2-Epoxy-4-vinylcyclohexane price More Price(12)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	152544	4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers 98%	106-86-5	250ml	$132	2026-04-30	Buy
TCI Chemical	E0956	1,2-Epoxy-4-vinylcyclohexane (mixture of isomers) >98.0%(GC)	106-86-5	25mL	$27	2026-04-30	Buy
TCI Chemical	E0956	1,2-Epoxy-4-vinylcyclohexane (mixture of isomers) >98.0%(GC)	106-86-5	250mL	$95	2026-04-30	Buy
TRC	E892145	1,2-Epoxy-4-vinylcyclohexane	106-86-5	2.5mL	$45	2021-12-16	Buy
SynQuest Laboratories	2309-1-01	4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers 98%	106-86-5	100g	$45	2021-12-16	Buy

Product number	Packaging	Price	Buy
152544	250ml	$132	Buy
E0956	25mL	$27	Buy
E0956	250mL	$95	Buy
E892145	2.5mL	$45	Buy
2309-1-01	100g	$45	Buy

1,2-Epoxy-4-vinylcyclohexane Chemical Properties,Uses,Production

Chemical Properties

Colorless liquid

Uses

Vinylcyclohexene monoxide is a chemical intermediate; it can be copolymerized with other epoxides to yield polyglycols having unsaturation available for further reaction.

Definition

ChEBI: 3-Vinyl-7-oxabicyclo[4.1.0]heptane is an oxacycle.

Synthesis Reference(s)

Tetrahedron Letters, 22, p. 2089, 1981 DOI: 10.1016/S0040-4039(01)93284-8

Synthesis

100-40-3

106-86-5

General Steps: 1. Add known amounts of 4-vinyl-1-cyclohexene and TBHP (tert-butyl hydroperoxide) without co-solvent in a 0.25 L capacity jacketed four-neck glass reactor. Set the feed molar ratio (FMR) of olefin to TBHP from 1:1 to 10:1. 2. Start the stirrer and adjust the stirring rate to 300-600 rpm. Heat the reaction mixture through the water bath and reactor jacket, and monitor the temperature using a digital thermocouple to ensure that the temperature of the reaction mixture stabilizes in the range of 323-353 K, with a fluctuation of no more than ±0.5 K. 3. When the reaction mixture reaches a constant temperature, set the FMR to 1:1 to 10:1, without adding co-solvent. 3. When the reaction mixture reached a constant temperature, a known amount of polymer loaded catalyst (0.15-0.6 mol Mo) was added. The time of catalyst addition was recorded as the reaction onset time (t = 0) and an initial sample was taken immediately. 4. Samples were taken at specific time intervals during the reaction and analyzed using Shimadzu GC-2014 gas chromatography (GC). 5. The experimental results showed that the PBI.Mo and Ps.AMP.Mo catalysts exhibited high selectivity in the epoxidation reaction of 4-vinyl-1-cyclohexene, which predominantly yielded 1,2-epoxy-4-vinylcyclohexane, and the GC analyses did not detect terminal or dicyclic oxide products. Detailed results of the batch experiments are discussed in Sect.

Toxics Screening Level

The initial threshold screening level (ITSL) for 1,2-epoxy-4-vinylcyclohexane is 6.0 μg/m3 based on an annual averaging time.

References

[1] RSC Advances, 2014, vol. 4, # 61, p. 32054 - 32062
[2] Applied Catalysis A: General, 2013, vol. 466, p. 142 - 152
[3] Journal of the American Chemical Society, 2009, vol. 131, # 36, p. 12890 - 12891
[4] Patent: CN108101868, 2018, A. Location in patent: Paragraph 0027-0068
[5] Journal of the Chemical Society - Perkin Transactions 1, 1997, # 21, p. 3115 - 3116

1,2-Epoxy-4-vinylcyclohexane Preparation Products And Raw materials

Raw materials

4-Vinyl-1-cyclohexene

Preparation Products

2-(3,4-epoxycyclohexyl)ethylmethyldiethosysilane 2-(3,4-EPOXYCYCLOHEXYL) ETHYLMETHYL DIMETHOXYSILANE

1,2-Epoxy-4-vinylcyclohexane Suppliers

Global( 271)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	+8615350571055	Sibel@chuanghaibio.com	China	8738	58
Hebei Fengjia New Material Co., Ltd	+86-0311-87836622 +86-18712993135	sales01@tairunfaz.com	China	8051	58
Hebei Longbang Technology Co., LTD	+86-18633929156	admin@hblongbang.com	China	972	58
HebeiShuoshengImportandExportco.,Ltd	+86-18532138899	L18532138899@163.com	China	939	58
Hebei Zhuanglai Chemical Trading Co Ltd	+86-16264648883	niki@zlchemi.com	China	7245	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29640	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	13843	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21590	55
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418679 +8618949832763	info@tnjchem.com	China	2988	55
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29819	58

Supplier	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	58
Hebei Fengjia New Material Co., Ltd	58
Hebei Longbang Technology Co., LTD	58
HebeiShuoshengImportandExportco.,Ltd	58
Hebei Zhuanglai Chemical Trading Co Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Hefei TNJ Chemical Industry Co.,Ltd.	55
career henan chemical co	58

View Lastest Price from 1,2-Epoxy-4-vinylcyclohexane manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-04-30	1,2-Epoxy-4-vinylcyclohexane 106-86-5	US $0.00 / Kg/Drum	1KG	98%min	20 tons	WUHAN FORTUNA CHEMICAL CO., LTD
2026-03-20	1,2-Epoxy-4-vinylcyclohexane 106-86-5	US $0.00-0.00 / KG	1KG	99%	10 mt	Hebei Chuanghai Biotechnology Co., Ltd
2025-12-01	1,2-Epoxy-4-vinylcyclohexane 106-86-5	US $0.00-0.00 / KG	1KG	99%	10000KGS	Shaanxi Dideu New Materials Co. Ltd

1,2-Epoxy-4-vinylcyclohexane
106-86-5
US $0.00 / Kg/Drum
98%min
WUHAN FORTUNA CHEMICAL CO., LTD

1,2-Epoxy-4-vinylcyclohexane
106-86-5
US $0.00-0.00 / KG
99%
Hebei Chuanghai Biotechnology Co., Ltd

1,2-Epoxy-4-vinylcyclohexane
106-86-5
US $0.00-0.00 / KG
99%
Shaanxi Dideu New Materials Co. Ltd

1,2-Epoxy-4-vinylcyclohexane Spectrum

1,2-Epoxy-4-vinylcyclohexane(106-86-5)¹HNMR 1,2-Epoxy-4-vinylcyclohexane(106-86-5)FT-IR 1,2-Epoxy-4-vinylcyclohexane(106-86-5)IR

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1,2-EPOXY-4-VINYLCYCLOHEXANE 3-VINYL-7-OXABICYCLO[4.1.0] HEPTANE 3-ETHENYL-7-OXABICYCLO[4.1.0]HEPTANE 4-VINYL-1-CYCLOHEXENE 1,2-EPOXIDE 4-Vinyl-1,2-epoxycyclohexane 4-Vinylcyclohexane 1,2-epoxide 4-Vinylcyclohexane monoepoxide 4-vinylcyclohexane,1,2-epoxide 4-Vinylcyclohexene monoxide 4-Vinylcyclohexene oxide 4-Vinylcyclohexene-1,2-epoxide 4-vinylcyclohexenemonoxide 7-Oxabicyclo(4.1.0)heptane, 3-vinyl- EP-101 Epoxide 101 Vinyl cyclohexane monoxide VINYL(4-)-1-CYCLOHEXANE-1,2-EPOXIDE 1-Vinyl-3,4-epoxycyclohexane 3,4-Epoxycyclohexylethylene Unoxat epoxide 101 unoxatepoxide101 Vinylcyclohexene monoxide vinylcyclohexenemonoxide 3-ethenyl-7-oxabicyclo[4.1.0]heptan 3-vinyl-7-oxabicyclo(4.1.0)heptan epoxide101 4-VINYL-1-CYCLOHEXENE 1,2-EPOXIDE, 98%, MIXTURE OF ISOMERS 4-VINYL-1-CYCLOHEXENE 1,2-EPOXIDE, 99% MIXTURE OF ISOMERS 7-Oxabicyclo4.1.0heptane, 3-ethenyl- 4-vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers 4-Vinylcyclohexane-1-oxide 4-Vinylcyclohexene monoepoxide 1,2-Vinylcyclohexene monoepoxide 3-Vinylcyclohexene oxide 4-Vinyl-7-oxabicyclo[4.1.0]heptane 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers ,98% [mixture of isomers] 4-Vinyl-1-cyclohexen 1,2-epoxide VINYLCYCLOHEXENE1,2-EPOXIDE 3-VINYL-7-OXABICYCLOHEPTANE VINYLCYCLOHEXENE1,2-MONOEPOXIDE 4-Vinyl-1-cyclohexene 1,2-epoxide, Mixture of isoMers 98% 3-Vinyl-7-oxabicyclo[4.1.0]heptane (UVR6100) 1,2-Epoxy-4-vinylcyclohexane (Mixture of isoMers) 4-ethenyl-7-oxabicyclo[4.1.0]heptane 2-Epoxy-4-vinylcyclohexane 1,2-Epoxy-4-vinylcyclohexane(mixtureofisomers)> ohexene 1,2-epoxide, mixture of isomers 1,2-EPOXY-4-VINYLCYCLOHEXANE CAS NO.:106-86-5 4-Vinyl-1-cyclohexane-1,2-epoxide 1,2-Epoxy-4-vinylcyclohexan 4-VinyChemicalbookl-1,2-epoxycyclohexane 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers,98% (stabilized with MEHQ) 4-Vinyl epoxycyclohexane 106-86-5 ALKENE Monomers Polymer Science Vinyl Halides, Amines, Amides, and Other Vinyl Monomers