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Triethoxysilane

CAS No.
998-30-1
Chemical Name:
Triethoxysilane
Synonyms
TES;TRIES;triethoxy-silan;Silane, triethoxy-;DK967;CT2500;HSi(OC2H5)3;TRIETHOXYSILANE;Triethoxysilicane;Triethoxysilane,96%
CBNumber:
CB5356887
Molecular Formula:
C6H16O3Si
Molecular Weight:
164.27
MDL Number:
MFCD00009061
MOL File:
998-30-1.mol
MSDS File:
SDS
Last updated:2024-04-19 20:05:26

Triethoxysilane Properties

Melting point -170°C
Boiling point 134-135 °C(lit.)
Density 0.89 g/mL at 25 °C(lit.)
vapor pressure 9.21hPa at 20℃
refractive index n20/D 1.377(lit.)
Flash point 80 °F
storage temp. Store at 0-5°C
solubility sol diethyl ether, THF, alkanes, aromatic and chlorinated solvents.
form A liquid
Specific Gravity 0.8753
Viscosity 0.76mm2/s
Water Solubility Insoluble in water. Soluble in organic solvents.
Sensitive Moisture Sensitive
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
BRN 1738989
Stability Stable, but moisture sensitive. Flammable. Incompatible with strong oxidizing agents, strong acids, strong bases.
InChIKey QQQSFSZALRVCSZ-UHFFFAOYSA-N
CAS DataBase Reference 998-30-1(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 8T460WDH89
NIST Chemistry Reference Silane, triethoxy-(998-30-1)
EPA Substance Registry System Triethoxysilane (998-30-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS06
Signal word  Danger
Hazard statements  H226-H302-H315-H318-H330
Precautionary statements  P210-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  T+,C,T
Risk Statements  10-26-34-23/24/25
Safety Statements  26-28-36/37/39-45
RIDADR  UN 3384 6.1/PG 1
WGK Germany  3
RTECS  VV6682000
10-21
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29209090
NFPA 704
3
4 0

Triethoxysilane price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 390143 Triethoxysilane 95% 998-30-1 10ml $54.3 2024-03-01 Buy
Sigma-Aldrich 390143 Triethoxysilane 95% 998-30-1 50ml $164 2024-03-01 Buy
Alfa Aesar B22063 Triethoxysilane 96% 998-30-1 10g $45.3 2024-03-01 Buy
Alfa Aesar B22063 Triethoxysilane 96% 998-30-1 50g $136 2024-03-01 Buy
Alfa Aesar B22063 Triethoxysilane 96% 998-30-1 250g $490 2024-03-01 Buy
Product number Packaging Price Buy
390143 10ml $54.3 Buy
390143 50ml $164 Buy
B22063 10g $45.3 Buy
B22063 50g $136 Buy
B22063 250g $490 Buy

Triethoxysilane Chemical Properties,Uses,Production

Description

Triethoxysilane is an organosilicon compound with the formula HSi(OC2H5)3. It is a colourless liquid used in precious metal-catalysed hydrosilylation reactions. The resulting triethoxysilyl groups are often valued for attachment to silica surfaces.Compared to most compounds with Si-H bonds, triethoxysilane exhibits relatively low reactivity. Like most silyl ethers, triethoxysilane is susceptible to hydrolysis. As reducing agent, triethoxysilane can for example be used in reduction of amides, reduction of carbonyl compounds in the presence of cobalt(II) chloride as catalyst, Cu-catalyzed reductive hydroxymethylation of styrenes, and Rh-catalyzed hydrodediazoniation.

Chemical Properties

Colorless, clear liquid

Physical properties

bp 134–135 °C; d 0.89 g cm?3.

Uses

Triethoxysilane is useful reagent for the hydrosilylation of carbon–carbon multiple bonds; reducing agent for carbonyl groups

Uses

Triethoxysilane is used in metal catalyzed hydrosilylation reactions.

Application

Reduces esters in the presence of zinc hydride catalyst. Reduces aldehydes and ketones to alcohols via the silyl ethers in presence of fluoride ion. Gives 1,2-reduction of enones to allyl alcohols.

General Description

Liquid. Used as a reducing agent.

Air & Water Reactions

May become pyrophoric, by generation of silane

Reactivity Profile

Triethoxysilane has been involved in cases where Triethoxysilane has disproportionated, generating silane (SiH4) which has a history of being pyrophoric.

Health Hazard

Toxicity is similar to silanes. Silanes are moderately irritating to skin, eyes, and mucous membranes. Silane compounds are toxic.

Fire Hazard

When heated to decomposition, Triethoxysilane emits acrid smoke and fumes.

Flammability and Explosibility

Highly flammable

Safety Profile

Poison by intravenous route.Moderately toxic by inhalation. Flammable liquid. Whenheated to decomposition it emits acrid smoke andirritating fumes.

Purification Methods

Fractionate it using a column packed with glass helices of ca 15 theoretical plates in an inert atmosphere. Store it in aliquots in sealed ampoules because it is sensitive to moisture. [Spauschus et al. J Am Chem Soc 72 1377 1950, MacKenzie et al. J Am Chem Soc 72 2032 1950, Havill et al. J Org Chem 13 280 1948, Beilstein 1 IV 1359.]

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View Lastest Price from Triethoxysilane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Triethoxysilane pictures 2024-04-20 Triethoxysilane
998-30-1
US $2.00 / kg 1kg 99.8% 10000ton Ouhuang Engineering Materials (Hubei) Co., Ltd
Triethoxysilane pictures 2024-04-20 Triethoxysilane
998-30-1
US $2.00 / kg 1kg 99.8% 10000ton Ouhuang Engineering Materials (Hubei) Co., Ltd
Triethoxysilane pictures 2024-01-14 Triethoxysilane
998-30-1
US $8.00-0.60 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
  • Triethoxysilane pictures
  • Triethoxysilane
    998-30-1
  • US $2.00 / kg
  • 99.8%
  • Ouhuang Engineering Materials (Hubei) Co., Ltd
  • Triethoxysilane pictures
  • Triethoxysilane
    998-30-1
  • US $2.00 / kg
  • 99.8%
  • Ouhuang Engineering Materials (Hubei) Co., Ltd
  • Triethoxysilane pictures
  • Triethoxysilane
    998-30-1
  • US $8.00-0.60 / KG
  • 99%
  • Henan Fengda Chemical Co., Ltd
CT2500 Triethoxysilane ((C2H5O)3SiH) Triethoxysilicane TRIETHOXYSILANE Triethoxysilane,96% Triethoxysilaneelectronicgradeavailable HSi(OC2H5)3 Triethoxysilyl hydride Triethoxysilane,95% Tris(ethyloxy)silane 4-bromooctafluorobutanetriethoxysilane Silicon triethoxide Tri-substituted Silane Reducing Agent Recombinant Human Testin/TES Protein, His Tag triethoxy-silan Silane, triethoxy- TES TRIES Triethoxysilane TES DK967 998-30-1 C2H5O3SiH CH3CH2O3SiH C6H15O3Si Organometallic Reagents Organosilicon Others Si-O Compounds Trialkoxysilanes Si-H Compounds Si (Classes of Silicon Compounds) OthersSilsesquioxanes: POSS? Nanohybrids RSi(OR)3Organometallic Reagents Organometallic Reagents Organosilicon POSS? Precursors and Intermediates Alkoxy Silanes Hydrogensilanes Hydrogensiloxanes Reducing Agents Si (Classes of Silicon Compounds) Si-H Compounds Si-O Compounds Trialkoxysilanes