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Chemical Name:
HEXAHYDRO-P-XYLENE;DIMETHYLCYCLOHEXANE;dimethylcyclohexanes;p-Dimethylcyclohexane;1,4-DIMETHYLCYCLOHEXANE;1,4-Dimethylcyclohexane,c&t;1,4-DiMethylcyclohexane 1,4-Dimethylcyclohexane(c,t);CIS-TRANS-1,4-DIMETHYLCYCLOHEXANE;1,4-dimethylcyclohexane cis-trans mixture
Molecular Formula:
Formula Weight:
MOL File:


Melting point:
−87 °C(lit.)
Boiling point:
120 °C(lit.)
0.773 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.426(lit.)
Flash point:
60 °F
CAS DataBase Reference
589-90-2(CAS DataBase Reference)
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  F,Xn,N
Risk Statements  11-38-51/53-65-67
Safety Statements  9-16-33-61-62
RIDADR  UN 2263 3/PG 2
WGK Germany  2
HazardClass  3.1
PackingGroup  II
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P331 Do NOT induce vomiting.
P391 Collect spillage. Hazardous to the aquatic environment
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to..…

NFPA 704

Diamond Hazard Value Description
2 0
Health   2 Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury (e.g. diethyl ether, ammonium phosphate, iodine)
Flammability   3 Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions . Liquids having a flash point below 22.8 °C (73 °F) and having a boiling point at or above 37.8 °C (100 °F) or having a flash point between 22.8 and 37.8 °C (73 and 100 °F). (e.g. gasoline, acetone)
Instability   0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)

(NFPA, 2010)

1,4-DIMETHYLCYCLOHEXANE price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 110507 1,4-Dimethylcyclohexane, mixture of cis and trans 99% 589-90-2 5g $42.1 2018-11-13 Buy
TCI Chemical D0700 1,4-Dimethylcyclohexane (cis- and trans- mixture) >98.0%(GC) 589-90-2 25mL $61 2018-11-22 Buy
TCI Chemical D0700 1,4-Dimethylcyclohexane (cis- and trans- mixture) >98.0%(GC) 589-90-2 500mL $458 2018-11-22 Buy

1,4-DIMETHYLCYCLOHEXANE Chemical Properties,Uses,Production

Chemical Properties

clear colorless liquid

General Description

Clear colorless liquids with a petroleum-like odor. Flash point between 51 - 61°F. Less dense than water and insoluble in water. Vapors heavier than air.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Saturated aliphatic hydrocarbons, such as 1,4-DIMETHYLCYCLOHEXANE, may be incompatible with strong oxidizing agents like nitric acid. Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, aliphatic saturated hydrocarbons are mostly unreactive. They are not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Purification Methods

Free it from olefins by shaking with conc H2SO4, washing with water, drying and fractionally distilling it. [Haggis & Owen J Chem Soc 411 1953, Beilstein 5 III 102, 5 IV 122.]

1,4-DIMETHYLCYCLOHEXANE Preparation Products And Raw materials

Raw materials

Preparation Products


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