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ChemicalBook >> CAS DataBase List >>(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene

(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene

(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene Structure
(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene structure
CAS No.
1221746-66-2
Chemical Name:
(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene
Synonyms
)-2-[1-(di-t-butyL;JoSPOphos SL-J688-2;(R,S(p), R(SPO)-1-PhenyL;(R,S(p), R(SPO)-1-Phenylphosphinoyl)-2-[1-(di-t-butylphosphino)ethyl]ferrocene;(S,R(p),S(SPO)-1-Phenylphosphinoyl)-2-[1-(tert-butylphosphino)ethyl]-ferrocene;(S)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene;(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene;(R)Fc-1-[(S)P-Phenylphosphinoyl]-2-[(S)-1-(di-tertbutylphosphino)ethyl]ferrocene;(R,S(p), R(SPO)-1-Phenylphosphinoyl)-2-[1-(t-butylphosphino)ethyl]ferrocene JoSPOphos;(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene >=97%
CBNumber:
CB72638008
Molecular Formula:
C26H30FeOP2
Molecular Weight:
476.32
MDL Number:
MFCD19105637
MOL File:
1221746-66-2.mol
Last updated:2023-04-23 13:52:06
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(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene Properties

storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color orange
Stability store cold

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
WGK Germany  3
HS Code  29319090

(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 26-1269 (S,R(p),S(SPO)-1-Phenylphosphinoyl)-2-[1-(di-t-butylphosphino)ethyl]ferrocene, min. 97% JoSPOphos min. 97% JoSPOphos 1221746-66-2 100mg $96 2024-03-01 Buy
Strem Chemicals 26-1269 (S,R(p),S(SPO)-1-Phenylphosphinoyl)-2-[1-(di-t-butylphosphino)ethyl]ferrocene, min. 97% JoSPOphos min. 97% JoSPOphos 1221746-66-2 500mg $355 2024-03-01 Buy
Strem Chemicals 26-1269 (S,R(p),S(SPO)-1-Phenylphosphinoyl)-2-[1-(di-t-butylphosphino)ethyl]ferrocene, min. 97% JoSPOphos min. 97% JoSPOphos 1221746-66-2 2g $1207 2024-03-01 Buy
Strem Chemicals 26-1269 (S,R(p),S(SPO)-1-Phenylphosphinoyl)-2-[1-(di-t-butylphosphino)ethyl]ferrocene, min. 97% JoSPOphos min. 97% JoSPOphos 1221746-66-2 10g $4824 2024-03-01 Buy
Strem Chemicals 26-1268 (R,S(p), R(SPO)-1-Phenylphosphinoyl)-2-[1-(di-t-butylphosphino)ethyl]ferrocene, min. 97% JoSPOphos 1221746-66-2 500mg $278 2021-12-16 Buy
Product number Packaging Price Buy
26-1269 100mg $96 Buy
26-1269 500mg $355 Buy
26-1269 2g $1207 Buy
26-1269 10g $4824 Buy
26-1268 500mg $278 Buy

(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene Chemical Properties,Uses,Production

Reaction

  1. Ligands used for the rhodium-catalyzed asymmetric hydrogenation of functionalized alkenes, α- and β- ketoesters.
  2. Ligand for rhodium -catalyzed enantioselective formation of tertiary and quaternary allylic C–N bonds via allylation of tetrazoles.
  3. Ligand for rhodium-catalyzed highly regio- and enantioselective addition of pyrazoles to terminal allenes.
Reactions of 1221746-66-2_1
Reactions of 1221746-66-2_2

Chemical Properties

Yellow powder

General Description

sold in collaboration with Solvias AG

(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene Preparation Products And Raw materials

Raw materials

Preparation Products

(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene Suppliers

Global( 23)Suppliers
Supplier Tel Email Country ProdList Advantage
Hangzhou MolCore BioPharmatech Co.,Ltd. 		+86-057181025280; +8617767106207 sales@molcore.com China 49739 58
Aladdin Scientific 		+1-833-552-7181 sales@aladdinsci.com United States 52927 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
BeiJing Hwrk Chemicals Limted 0757-86329057 18501085097 sales3.gd@hwrkchemical.com China 7639 55
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Bide Pharmatech Ltd. 400-1647117 15221909166 product02@bidepharm.com China 41438 60
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2654 58
Aikon International Limited 025-66113011 18112977050 sales01@aikonchem.com China 16028 58
Domole Scientific 13275595566 15001012717 domole.infsci@outlook.com China 585 58
Supplier Advantage
Hangzhou MolCore BioPharmatech Co.,Ltd. 		58
Aladdin Scientific 		58
J & K SCIENTIFIC LTD. 76
BeiJing Hwrk Chemicals Limted 55
Energy Chemical 61
Bide Pharmatech Ltd. 60
Sigma-Aldrich 80
LaaJoo 58
Aikon International Limited 58
Domole Scientific 58
(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene (S,R(p),S(SPO)-1-Phenylphosphinoyl)-2-[1-(tert-butylphosphino)ethyl]-ferrocene (S, R(p), S(SPO)-1-Phenylphosphinoyl)-2-[1-(t-butylphosphino)ethyl]ferrocene, Min. 97% JoSPOphos (R,S(p), R(SPO)-1-Phenylphosphinoyl)-2-[1-(t-butylphosphino)ethyl]ferrocene, Min. 97% JoSPOphos (2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-[(S)-phenylphosphinyl]ferrocene (acc to CAS) JoSPOphos SL-J688-2 (RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene >=97% (R,S(P),R(SPO)-1-PHENYLPHOSPHINOYL)-2-[1-(DI-T-BUTYLPHOSPHINO)ETHYL]FERROCENE,MIN.97%JOSPOPHOS cyclopenta-1,3-diene:(Z)-[2-[(1S)-1-ditert-butylphosphanylethyl]cyclopenta-2,4-dien-1-ylidene]-oxido-phenylphosphanium:iron(2+) (R,S(p), R(SPO)-1-Phenylphosphinoyl)-2-[1-(t-butylphosphino)ethyl]ferrocene JoSPOphos (R,S(p), R(SPO)-1-Phenylphosphinoyl)-2-[1-(di-t-butylphosphino)ethyl]ferrocene (R,S(p), R(SPO)-1-PhenyL )-2-[1-(di-t-butyL (R)Fc-1-[(S)P-Phenylphosphinoyl]-2-[(S)-1-(di-tertbutylphosphino)ethyl]ferrocene (S)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene 1221746-66-2 C26H36FeOP2 JoSPOphos Series Chiral Phosphine Ferrocene Series