Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
- CAS No.
- 1621274-17-6
- Chemical Name:
- Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
- Synonyms
- Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-met...;(1,1'-bis(diphenylphosphino)diron)(2'-methylamino-1,1'-biphenyl-2-yl)methylsulfonylacidpaladium(I-I);Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2’-methylamino-1,1’-biphenyl-2-yl)palladium(II);Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);DPPF PD G4 Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);(SP-4-3)-[1-(Diphenylphosphino-κP)-1′-(diphenylphosphino)ferrocene](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium;(SP-4-3)-[1-(Diphenylphosphino-κP)-1′-(diphenylphosphino)ferrocene](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium (ACI);(SP-4-3)-[1-(Diphenylphosphino-kappap)-1'-(diphenylphosphino)-ferrocene](methanesulfonato-kappao)[2'-(methylamino-kappan)-biphenyl-2-yl-kappac]palladium
- CBNumber:
- CB76187915
- Molecular Formula:
- C48H35FeNO3P2PdS
- Molecular Weight:
- 930.08
- MDL Number:
- MFCD30718058
- MOL File:
- 1621274-17-6.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| DPPF Pd G4 95% | 900454 | 250mg | $150 |
| DPPF Pd G4 95% | 900454 | 1g | $535 |
| (SP-4-3)-[1-(Diphenylphosphino-κP)-1′-(diphenylphosphino)ferrocene](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium ≥98% | AS708397 | 5g | $594 |
| (SP-4-3)-[1-(Diphenylphosphino-κP)-1′-(diphenylphosphino)ferrocene](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium 98+% | BD01090381 | 5g | $600 |
| (SP-4-3)-[1-(Diphenylphosphino-κP)-1′-(diphenylphosphino)ferrocene](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium 98+% | A1155293 | 5g | $600 |
Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) Properties
| Melting point | 201 °C |
|---|---|
| storage temp. | -20°C |
| form | powder |
| Appearance | Orange to reddish brown Solid |
| SMILES | CNC1=C(C2=C([Pd]OS(=O)(C)=O)C=CC=C2)C=CC=C1.[C]3(P(C4=CC=CC=C4)C5=CC=CC=C5)[C][C][C][C]3.[C]6(P(C7=CC=CC=C7)C8=CC=CC=C8)[C][C][C][C]6.[Fe] |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS09 |
|---|---|
| Signal word | Warning |
| Hazard statements | H320-H410 |
| Precautionary statements | P501-P273-P264-P391-P337+P313-P305+P351+P338 |
| WGK Germany | WGK 3 |
| Storage Class | 11 - Combustible Solids |
Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) price
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 900454 | DPPF Pd G4 95% | 1621274-17-6 | 250mg | $150 | 2026-04-30 | Buy |
| Sigma-Aldrich | 900454 | DPPF Pd G4 95% | 1621274-17-6 | 1g | $535 | 2026-04-30 | Buy |
| Arctom | AS708397 | (SP-4-3)-[1-(Diphenylphosphino-κP)-1′-(diphenylphosphino)ferrocene](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium ≥98% | 1621274-17-6 | 5g | $594 | 2021-12-16 | Buy |
| BLDpharm | BD01090381 | (SP-4-3)-[1-(Diphenylphosphino-κP)-1′-(diphenylphosphino)ferrocene](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium 98+% | 1621274-17-6 | 5g | $600 | 2021-12-16 | Buy |
| Ambeed | A1155293 | (SP-4-3)-[1-(Diphenylphosphino-κP)-1′-(diphenylphosphino)ferrocene](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium 98+% | 1621274-17-6 | 5g | $600 | 2021-12-16 | Buy |
Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) Chemical Properties,Uses,Production
Uses
DPPF Pd G4 is a fourth generation (G4) Buchwald precatalyst that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations found when using the third generation precatalysts. It is air, moisture, and thermally-stable and shows good solubility in common organic solvents.
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 +8618813727289 | contact@trustwe.com | China | 5742 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25356 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 52923 | 58 | |
| Anhuyan (Hainan) Biotechnology Co., LTD | +8618163349544 | mollylucking@foxmail.com | China | 3000 | 58 |
| Shanghai Scibiotron Pharmaceutical Co., Ltd | +86-16621589600 | contact@scibiotron.com | China | 5999 | 58 |
| Adamas Reagent, Ltd. | 400-6009262 15618770481 | yhx@titansci.com | China | 14100 | 59 |
| Nanjin Cynthia chemicals Technology Co.,Ltd | 0550-5618439 15951861180 | cynthiachem@163.com | China | 291 | 62 |
| WuHan Taiyukaishang Chemical Co., Ltd. | 027-027-87680032 18963957250 | taiyuchem@163.com | China | 180 | 55 |
| Shanghai Haozhixiang Biotechnology Co., Ltd | 526763801 13301653310 | 526763801@qq.com | China | 9445 | 55 |
| Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. | 0371-65511006 18737115891;18625597674 | info@kingorgchem.com;sales@kingorgchem.com | China | 823 | 55 |





