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(1S,4S,5S)-5-(4-fluorophenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane

(1S,4S,5S)-5-(4-fluorophenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane Structure
(1S,4S,5S)-5-(4-fluorophenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane structure
CAS No.
Chemical Name:
(1S,4S,5S)-5-(4-fluorophenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane
Synonyms
Exo-1-Naphthyl Kwon [2.2.1] Bicyclic Phosphine;(1S,4S,5S)-5-(4-fluorophenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane
CBNumber:
CB92886324
Molecular Formula:
C18H19FNO2PS
Molecular Weight:
363.3861242
MDL Number:
MFCD28016349
MOL File:
Mol file
Last updated:2023-04-23 13:52:06
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(1S,4S,5S)-5-(4-fluorophenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane Properties

storage temp. 2-8°C
form powder

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
WGK Germany  3

(1S,4S,5S)-5-(4-fluorophenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 798339 Exo-1-Naphthyl Kwon [2.2.1] Bicyclic Phosphine 100MG $143 2023-06-20 Buy
Product number Packaging Price Buy
798339 100MG $143 Buy

(1S,4S,5S)-5-(4-fluorophenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane Chemical Properties,Uses,Production

Uses

The bicyclic, chiral phosphine was developed by the Kwon Research Group.Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.

(1S,4S,5S)-5-(4-fluorophenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane Preparation Products And Raw materials

Raw materials

Preparation Products

(1S,4S,5S)-5-(4-fluorophenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane Suppliers

Global( 2)Suppliers
Supplier Tel Email Country ProdList Advantage
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Supplier Advantage
Sigma-Aldrich 80
(1S,4S,5S)-5-(4-fluorophenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane Exo-1-Naphthyl Kwon [2.2.1] Bicyclic Phosphine