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Zinc bromide

Description References
Zinc bromide
Zinc bromide
CAS No.
7699-45-8
Chemical Name:
Zinc bromide
Synonyms
ZnBr2;Dibromozinc;Zinc broMid;ZINC BROMIDE;zincdibromide;ZINC(II) BROMIDE;zincbromide(znbr2);ZINC BROMIDE, 98+%;Zinc bromide(solid);ZincbromidePURATREM
CBNumber:
CB9680793
Molecular Formula:
Br2Zn
Formula Weight:
225.2
MOL File:
7699-45-8.mol

Zinc bromide Properties

Melting point:
394 °C(lit.)
Boiling point:
697 °C
Density 
4.22
refractive index 
1.5452
Flash point:
650°C
storage temp. 
APPROX >0°C
solubility 
Soluble in alcohol, ether, acetone and tetrahydrofuran.
form 
beads
color 
White to pale cream
PH
4 (H2O, 20℃)(saturated solution)
Water Solubility 
soluble, 447 g/100 mL (20 ºC)
Sensitive 
Hygroscopic
Merck 
14,1029
Stability:
Stable. Forms explosive mixtures with sodium and potassium. Protect from moisture.
CAS DataBase Reference
7699-45-8(CAS DataBase Reference)
NIST Chemistry Reference
Zinc dibromide(7699-45-8)
EPA Substance Registry System
Zinc bromide (ZnBr2)(7699-45-8)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  C,N
Risk Statements  34-50/53-50-51/53-43-22
Safety Statements  26-36/37/39-45-60-61-29
RIDADR  UN 3260 8/PG 3
WGK Germany  3
RTECS  ZH1150000
3-21
TSCA  Yes
HS Code  2827 59 00
HazardClass  8
PackingGroup  II
Hazardous Substances Data 7699-45-8(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Zinc bromide price More Price(27)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 230022 Zinc bromide 99.999% trace metals basis 7699-45-8 10g $69.1 2018-11-13 Buy
Sigma-Aldrich 230022 Zinc bromide 99.999% trace metals basis 7699-45-8 50g $241 2018-11-13 Buy
TCI Chemical Z0013 Zinc Bromide >98.0%(T) 7699-45-8 25g $46 2018-11-22 Buy
TCI Chemical Z0013 Zinc Bromide >98.0%(T) 7699-45-8 300g $60 2018-11-22 Buy
Alfa Aesar 035725 Zinc bromide, ultra dry 99.999% (metals basis) 7699-45-8 5g $55.2 2018-11-20 Buy

Zinc bromide Chemical Properties,Uses,Production

Description

Zinc bromide (chemical formula: ZnBr2) is an inorganic compound consisting of zinc and bromide. It is manufactured through the reaction between zinc oxide (alternatively, zinc metal) with hydrobromic acid, alternatively by the reaction between zinc metal and bromine. It is a kind of Lewis acid in organic chemistry. It can be used as the electrolyte in the zinc bromide battery. In oil and natural gas industry, its related solution can be used to displace drilling mud. Moreover, its solution can be used as a transparent shield against radiation. Finally, it can be used as a catalyst for the Stereospecific and regioselective reaction between silacyclopropanes with carbonyl compounds.

References

https://en.wikipedia.org/wiki/Zinc_bromide
https://www.alfa.com/en/catalog/B22510/

Chemical Properties

White hygroscopic powder

Chemical Properties

Zinc bromide is an odorless white crystalline solid.

Uses

Optimal catalyst for stereospecific and regioselective reaction of silacyclopropanes with carbonyl compounds.1

Uses

Zinc bromide is a white crystalline powder prepared by dissolving zinc carbonate in hydrobromic acid. Zinc chloride (ZnCl2? is a white granular crystal made by the action of hydrochloric acid on zinc. Zinc iodide (ZnI2) is a white powder made by dissolving zinc in ionic acid. All of the zinc halides are soluble in water, alcohol, and ether. They were all used as halides for the collodion emulsion processes.

Uses

Making silver bromide collodion emulsions for photography; in the shielding of viewing windows for nuclear reactions.

General Description

A white crystalline noncombustible solid. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Zinc bromide is used in medicine, in photography.

Air & Water Reactions

Hygroscopic. Water soluble

Reactivity Profile

Acidic inorganic salts, such as Zinc bromide, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Health Hazard

Inhalation of dust may irritate nose and throat. Ingestion can cause irritation or corrosion of the alimentary tract; if large amount is swallowed and not thrown up, drowsiness and other symptoms of bromide poisoning may occur. Contact with eyes or skin causes irritation.

Potential Exposure

Zinc bromide is used in photography, rayon manufacturing and medicine

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

Shipping

UN3260 Corrosive solid, acidic, inorganic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Purification Methods

Heat ZnBr2 to 300o under vacuum (2x10-2 mm) for 1hour, then sublime it. [Wagenknecht & Juza Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1072 1965.]

Incompatibilities

Keep away from alkali metals. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, metallic sodium, or potassium. Store above 32 ℉/0℃.

Zinc bromide Preparation Products And Raw materials

Raw materials

Preparation Products


Zinc bromide Suppliers

Global( 196)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 22058 58
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0371-55170693
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Mainchem Co., Ltd.
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+86-0592-6210733 sales@mainchem.com CHINA 32764 55
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0086 158 5814 5714 (Mobile; WhatsApp; Telegram)
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86-0551-65418684 18949823763
86-0551-65418684 info@tnjchem.com China 1583 55
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022-89880739
022-66880086 sales@tjzxchem.com CHINA 560 58
Tianjin Zhongxin Chemtech Co., Ltd. 86(0)22-89880739
86(0)22-89880739 ext 8030 / 86-22-66880086 sales@tjzxchem.com China 554 60
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