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4-hydroxynaphthalene-1,5-disulphonic acid

CAS No.
117-56-6
Chemical Name:
4-hydroxynaphthalene-1,5-disulphonic acid
Synonyms
Schoellkopf's acid;α-Naphtholdisulfonic acid S;1-naphthol-4,8-disulfonic acid;8-Hydroxy-1,5-naphthalenedisulfonic acid;4-hydroxynaphthalene-1,5-disulfonic acid;4-Hydroxy-1,5-naphthalenedisulfonic acid;4-hydroxynaphthalene-1,5-disulphonic acid;1,5-Naphthalenedisulfonic acid, 4-hydroxy-
CBNumber:
CB9929654
Molecular Formula:
C10H8O7S2
Molecular Weight:
304.3
MDL Number:
MFCD00035854
MOL File:
117-56-6.mol
Last updated:2023-11-01 14:53:20

4-hydroxynaphthalene-1,5-disulphonic acid Properties

Density 1.816±0.06 g/cm3(Predicted)
pka -0.42±0.40(Predicted)
FDA UNII L6O8AVH6FU

4-hydroxynaphthalene-1,5-disulphonic acid Chemical Properties,Uses,Production

Chemical Properties

1-Hydroxynaphthalene-4,8-disulfonic acid [117-56-6]. (4-hydroxynaphthalene-1,5- disulfonicacid),Schollkopf ’s acid, deltaacid, oxy Chicago acid, C10H8O7S2, Mr 304.3: the sodium saltis readily solubleinwater, butthe barium saltis only sparingly soluble.Cold5 % oleumdehydrates 1-Hydroxynaphthalene-4,8-disulfonic acid to the sultone, whereas with hot 25 % oleum it undergoes sulfonation to give 1-hydroxynaphthalene-2,4,8-trisulfonic acid. Amination (Bucherer) gives 1-aminonaphthalene-4,8-disulfonic acid and caustic fusion gives 1,8-dihydroxynaphthalene-4-sulfonic acid. Diazo coupling and nitrosation take place in the 2-position.

Production Methods

1-Hydroxynaphthalene-8-sulfonic acid-1,8-sultone is heated with sulfuric acid at 80 – 90℃. The reaction mixture is then quenched by pouring into concentrated brine, whereby the sodium salt of 82 crystallizes. After isolation, this intermediate is hydrolyzed by heating with aqueous sodium carbonate and the product is isolated as its sodium salt after cooling.
4-hydroxynaphthalene-1,5-disulphonic acid synthesis

4-hydroxynaphthalene-1,5-disulphonic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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4-hydroxynaphthalene-1,5-disulphonic acid 1-naphthol-4,8-disulfonic acid 4-Hydroxy-1,5-naphthalenedisulfonic acid Schoellkopf's acid 8-Hydroxy-1,5-naphthalenedisulfonic acid α-Naphtholdisulfonic acid S 4-hydroxynaphthalene-1,5-disulfonic acid 1,5-Naphthalenedisulfonic acid, 4-hydroxy- 117-56-6