CI 15511
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CI 15511 속성
- 녹는점
- 138°; mp 176°
- 끓는 점
- 555.14°C (rough estimate)
- 밀도
- 1.3285 (rough estimate)
- 굴절률
- 1.5614 (estimate)
- 산도 계수 (pKa)
- pKb (20°) = 10.7, pKa = 9.3
- 수용성
- 579.1mg/L(15℃)
- CAS 데이터베이스
- 131-28-2
안전
CI 15511 C화학적 특성, 용도, 생산
개요
An alkaloid of opium (Papaver somniferum) was first isolated by Pelletier in 1832 but not characterized until some years later by Couerbe and Anderson, the latter assigning to it the formula C23H2909N which was accepted until Freund showed that it contains H20 of crystallization. The base remains in the mother liquors after removal of the major alkaloids. It forms slender, colourless needles or prisms of the trihydrate, m.p. 170°C. It is optically inactive and dissolves readily in alkalies forming metallic derivatives. It behaves as a weak, monoacidic base forming well-crystallized salts. The hydrochloride crystallizes with 5.5 H20 from cold, dilute HCI, or as the trihydrate from hot solutions. From MeOH it yields crystals with 1 mole of solvent, m.p. 190-2°C. The aurichloride forms reddish-yellow needles, m.p. 130°C and the picrate has m.p. 195°C. With chlorine water, followed by the addition of ammonia, it gives a characteristic blood-red colour while with dilute iodine solution, the solid alkaloid develops a blue colour. With ethyl nitrite, narceine forms an oximino derivative which, on exhaustive methylation, furnishes trimethylamine, hemipinic acid and 2-cyano-3- methoxy-4: s-methylenedioxy-1-vinylbenzene.Purification Methods
Recrystallise Narcein from water (as trihydrate). The styphnate has m 185-189o (from EtOH), and the picrate has m 200o (from EtOH). [Beilstein 19 H 370, 19 I 797, 19 II 386, 19 IV 4382.]참고 문헌
Couerbe., Annalen, 17,171 (1836)Anderson., ibid, 86, 182 (1853)
Roser., ibid, 247, 167 (1888)
Freund, Frankforter., ibid, 277,20 (1893)
Freund, Oppenheimer., Ber., 42, 1084 (1909)
CI 15511 준비 용품 및 원자재
원자재
준비 용품
CI 15511 공급 업체
글로벌( 13)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Alchem Pharmtech,Inc. | 8485655694 |
sales@alchempharmtech.com | United States | 63711 | 58 |
ShangHai Caerulum Pharma Discovery Co., Ltd. | 18149758185 |
sales-cpd@caerulumpharma.com | China | 3420 | 58 |
Jinan Ruisi Pharmaceutical Technology Co., LTD | 0531-69900633 18340090523 |
changyuan20@163.com | China | 1717 | 58 |
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. | 025-66113011 18112977050 |
cb5@aikonchem.com | China | 10529 | 58 |
CI 15511 관련 검색:
2-히드록시3-메톡시벤조산
2,3-Dihydroxybenzoic acid
3',4'-DIMETHOXY-2-PHENYLACETOPHENONE
PIPERONYL METHYL KETONE
(2,4-Dimethoxyphenyl)acetone
4'-Hydroxy-3'-methoxypropiophenone
2-[2-(3-Methoxyphenyl)ethyl]phenol
2-PHENETHYLBENZYL ALCOHOL
DESOXYANISOIN
CI 15511
6-Formyl-2,3-dimethoxybenzoic acid
3-METHOXYPHENYLACETONE
2,3-Dimethoxybenzoic acid
4'-METHOXY-2-PHENYLACETOPHENONE
2-(3-METHOXYPHENYL)ACETOPHENONE
O-PROPIONYLBENZOIC ACID
2-METHOXY-5-METHYLBENZOIC ACID
4-METHOXYPHTHALALDEHYDE