fumitremorgin B

fumitremorgin B 구조식 이미지
카스 번호:
12626-17-4
상품명:
fumitremorgin B
동의어(영문):
Lanosulin;Fumitremorgin;FUMITREMORGENB;fumitremorgin B;B Fumitremorgin B;(5aR)-1,2,3,5a,6,11,12,14aβ-Octahydro-5aβ,6β-dihydroxy-9-methoxy-11-(3-methyl-2-butenyl)-12α-(2-methyl-1-propenyl)-5H,14H-pyrrolo[1'',2'':4',5']pyrazino[1',2':1,6]pyrido[3,4-b]indole-5,14-dione;5H,14H-Pyrrolo[1'',2'':4',5']pyrazino[1',2':1,6]pyrido[3,4-b]indole-5,14-dione, 1,2,3,5a,6,11,12,14a-octahydro-5a,6-dihydroxy-9-methoxy-11-(3-methyl-2-buten-1-yl)-12-(2-methyl-1-propen-1-yl)-, (5aR,6S,12S,14aS)-
CBNumber:
CB11387239
분자식:
C27H33N3O5
포뮬러 무게:
479.57
MOL 파일:
12626-17-4.mol

fumitremorgin B 속성

녹는점
205-207 °C
끓는 점
724.3±60.0 °C(Predicted)
밀도
1.35±0.1 g/cm3(Predicted)
저장 조건
Store at -20°C
용해도
DMSO: Soluble,Methanol: Soluble
물리적 상태
고체
산도 계수 (pKa)
10.74±0.60(Predicted)

안전

fumitremorgin B C화학적 특성, 용도, 생산

개요

This tremorgenic alkaloid is highly toxic and is elaborated by Aspergillus jurnigatus. The structure given above has been determined from X-ray crystallography. The crystals are orthorhombic with space group P2 1212 1, a = 14.771, b = 24.925 and c = 7.321 A with Z = 4. The absolute configuration is based upon that of L( - )-proline formed by acid hydrolysis of the alkaloid.

정의

ChEBI: An organic heteropentacyclic compound that is a mycotoxic indole alkaloid produced by several fungi via a tryptophan-proline diketopiperazine intermediate.

참고 문헌

Yamazaki et al., Tetrahedron Lett., 27 (1975)

fumitremorgin B 준비 용품 및 원자재

원자재

준비 용품


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