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(2R,6R)-2-methyl-6-prop-1-enyl-piperidine

(2R,6R)-2-methyl-6-prop-1-enyl-piperidine 구조식 이미지

카스 번호:: 501-02-0

상품명:: (2R,6R)-2-methyl-6-prop-1-enyl-piperidine

동의어(영문):: Pinidine;(-)-Pinidine;2α-Methyl-6α-[(E)-1-propenyl]piperidine;(2R,6R)-2-methyl-6-prop-1-enyl-piperidine;(2R)-2-Methyl-6α-[(E)-1-propenyl]piperidine;Piperidine, 2-methyl-6-(1E)-1-propen-1-yl-, (2R,6R)-

CBNumber:: CB11515186

분자식:: C9H17N

포뮬러 무게:: 139.24

MOL 파일:: 501-02-0.mol

속성

안전

용도

(2R,6R)-2-methyl-6-prop-1-enyl-piperidine 속성

끓는 점: 176-7oC/751mm

밀도: 0.879±0.06 g/cm3(Predicted)

산도 계수 (pKa): 10.30±0.10(Predicted)

안전

(2R,6R)-2-methyl-6-prop-1-enyl-piperidine C화학적 특성, 용도, 생산

개요

A piperidine alkaloid isolated from Pinus jeffreyi, P. sabiniana Doug!., and P. torreyana, this base is a colourless liquid which is laevorotatory with [Ql~~9 - 10.5° and [Ql~j5 - 23.4° (c 1.88, EtOH). It yields a crystalline hydrochloride as colourless needles from EtOH-AcOEt, m.p. 244-6°C and a methiodide, m.p. 214-8°C. The structure has been determined by spectroscopic methods as 2-methyl-6-( trans-2-propeny I)-piperidine.

참고 문헌

Tallent, Stromberg, Horning.,J. Arner. Chern. Soc., 77,6361 (1955)
Tallent, Horning., ibid, 78,4467 (1956)
Hill, Chan, Joule., Tetrahedron, 21,147 (1965)

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