STEMONIDINE

STEMONIDINE 구조식 이미지
카스 번호:
85700-47-6
상품명:
STEMONIDINE
동의어(영문):
STEMONIDINE;Spiro[furan-2(5H),9'-[9H]pyrrolo[1,2-a]azepin]-5-one, decahydro-8'-methoxy-4-methyl-3'-[(2S,4S)-tetrahydro-4-methyl-5-oxo-2-furanyl]-, (2R,3'S,4R,5R,8'R,9'aS)-
CBNumber:
CB1414796
분자식:
C19H29NO5
포뮬러 무게:
351.44
MOL 파일:
Mol file

STEMONIDINE 속성

녹는점
116°C
CAS 데이터베이스
85700-47-6

안전

STEMONIDINE C화학적 특성, 용도, 생산

개요

This alkaloid occurs in the roots of Stemona japonica and behaves as a tertiary base. It has [α]25D - 7.65°C and is characterized as the hydrochloride which decomposes at 2600 C and the methiodide, decomposing at 2480 C. The alkaloid is not affected by HCI in either AcOH or EtOH and the oxidation products formed with KMn04 depend upon the conditions. If the oxidation is carried out in Me2CO a base is obtained which yields a crystalline methiodide, m.p. 235°C. On the other hand, KMn04 in dilute H2 S04 at lOoC yields two substances (a) a neutral compound, C16H230sN, m.p. 208°C; [α]D - 58.30 which contains a lactone ring and one methoxyl group and (b) a substance CllH170 4N, m.p. 202°C; [α]D - 24.17° which yields a semicarbazone, m.p. 258°C but contains no lactone group.
There is still ~ome doubt concerning the plant identity from which this alka_x0002_loid was isolated. Investigation by Suzuki suggested that it is not Stemona japonica as stated above but Stemona ovata Nakai.

참고 문헌

Suzuki.,J. Pharm. Soc., Japan, No. 352, 567 (1921)
Suzuki., ibid, 49, 78,457 (1929)
Suzuki., ibid, 51,43 (1931)
Suzuki., ibid, 54, 101 (1934)
Suzuki., ibid, 59, 184(1939)

STEMONIDINE 준비 용품 및 원자재

원자재

준비 용품


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