트리스(트리페닐포스핀)로듐(I) 염화물
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트리스(트리페닐포스핀)로듐(I) 염화물 속성
- 녹는점
- 245-250 °C (dec.)
- 끓는 점
- >170°C
- 밀도
- 1.363; d 1.379
- 증기압
- 0Pa at 25℃
- 저장 조건
- Keep in dark place,Inert atmosphere,Room temperature
- 용해도
- 대부분의 용매(예: 벤젠, 에탄올, 에 용해됨클로로포름, 디클로로메탄)에 용해되지만 포스핀이 해리됩니다. 용액에서 O{2}와 반응
- 물리적 상태
- 결정성 분말
- 색상
- 적갈색에서 적갈색까지
- 수용성
- 불용성
- 감도
- air sensitive
- Hydrolytic Sensitivity
- 4: no reaction with water under neutral conditions
- Merck
- 14,9758
- BRN
- 4581440
- 노출 한도
- ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
- InChIKey
- QEYYHUJFSQCTAE-UHFFFAOYSA-M
- LogP
- 5.69 at 20℃
- CAS 데이터베이스
- 14694-95-2(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | C,Xi | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 34-36/38 | ||
| 안전지침서 | 22-24/25-37/39-28A-26-15-45-36/37/39 | ||
| 유엔번호(UN No.) | 1759 | ||
| WGK 독일 | 1 | ||
| F 고인화성물질 | 8-10-23 | ||
| TSCA | Yes | ||
| HS 번호 | 28439090 |
트리스(트리페닐포스핀)로듐(I) 염화물 C화학적 특성, 용도, 생산
화학적 성질
magenta crystals용도
Tris(triphenylphosphine)rhodiu is also known as Wilkinson's catalyst and is commonly used to catalyze the hydrogenation of alkenes. Tris(triphenylphosphine)rhodiu is also used in the catalytic hydroboration of alkenes with catecholborane and pinacolborane and the selective 1,4-reduction of α, β-unsaturated carbonyl compounds.Purification Methods
It forms dark burgundy crystals from hot EtOH after refluxing for 30minutes. When the solution is heated for only 5minutes, orange crystals are formed. Heating the orange crystals in EtOH yields red crystals. Crystallisation from Me2CO gives the orange crystals. The two forms have similar IR spectra, but the X-ray diffraction patterns are slighly different. [Osborne et al. J Chem Soc (A) 1711 1966, Osborne & Wilkinson Inorg Synth X 67 1967, Bennett & Donaldson Inorg Chem 16 655 1977.] The solubilities are as follows: in CH2Cl2 ~2% (25o), in toluene 0.2% (25o), and less soluble in Me2CO, MeOH, BuOH and AcOH, but insoluble in pet ethers and cyclohexane. It reacts with donor solvents such as pyridine, DMSO and MeCN.트리스(트리페닐포스핀)로듐(I) 염화물 준비 용품 및 원자재
원자재
준비 용품
트리스(트리페닐포스핀)로듐(I) 염화물 공급 업체
글로벌( 416)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Weifang Wehibest Supply Chain Co.,Ltd | +8613583620690 |
hotspotbiotech@163.com | China | 926 | 58 |
| Shanghai UCHEM Inc. | +862156762820 +86-13564624040 |
sales@myuchem.com | China | 6710 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 15928 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21691 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 |
product@chemlin.com.cn | CHINA | 3012 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 32480 | 60 |
| AB PharmaTech,LLC | 323-480-4688 |
United States | 989 | 55 | |
| career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
| Nanjing Dolon Biotechnology Co.,Ltd. | 18905173768 |
sales@dolonchem.com | CHINA | 2972 | 58 |
트리스(트리페닐포스핀)로듐(I) 염화물 관련 검색:
트리페닐포스핀 로듐 트리염화물 로디움(II) 아세틸아세토네이트 포스핀(기체) 페닐포스핀 (트리페닐포스포라닐리덴)아세트알데히드 트리스(트리페닐포스핀)로듐(I) 염화물 로듐
Tris(dibenzylideneacetone)dipalladium-chloroform adduct
CHLOROTRIS(TRIPHENYLPHOSPHINE)COBALT(I)
Tri-tert-butylphosphine tetrafluoroborate
Tris(1-Chloro-2-Propyl) Phosphate
cis-Bis(triphenylphosphine)platinum(II) chloride
Tris(triphenylphosphine)ruthenium(II) chloride
Tris(dibenzylideneacetone)dipalladium
Carbonylchlorohydrotris(triphenylphosphine)ruthenium
Tris(dibenzylideneacetone)dipalladium
Ruthenium(II) chloride mesitylene dimer