Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos]

Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos] 구조식 이미지
카스 번호:
1025476-84-9
상품명:
Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos]
동의어(영문):
RU(OAC)2[(S)-DTBM-SEGPHOS;e}ruthenium(II) Ru(OAc)2[(S)-dtbm-seg;Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyL;Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II);Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II);Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos;Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos];Diacetato{(S)-(+)-5,5''-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4''-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos];Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos(R)]
CBNumber:
CB22527044
분자식:
C78H106O12P2Ru
포뮬러 무게:
1398.686562
MOL 파일:
1025476-84-9.mol
MSDS 파일:
SDS

Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos] 속성

물리적 상태
고체
물리적 상태
단단한 모양
색상
노란색에서 갈색을 띤 빨간색에서 진한 녹색까지
감도
air sensitive
CAS 데이터베이스
1025476-84-9

안전

Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos] C화학적 특성, 용도, 생산

화학 반응

  1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters.
  2. Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
  3. Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone.
Reactions of 1025476-84-9

Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos] 준비 용품 및 원자재

원자재

준비 용품


Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dtbm-segphos] 공급 업체

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