metaphanine

metaphanine 구조식 이미지
카스 번호:
1805-86-3
상품명:
metaphanine
동의어(영문):
metaphanine;8β,10β-Epoxy-8-hydroxy-3,4-dimethoxy-17-methylhasubanan-7-one
CBNumber:
CB41480649
분자식:
C19H23NO5
포뮬러 무게:
345.38962
MOL 파일:
1805-86-3.mol

metaphanine 속성

녹는점
232°; mp 205-206° for the dl-form (Ibuka)
산도 계수 (pKa)
6.03(at 25℃)

안전

metaphanine C화학적 특성, 용도, 생산

개요

This alkaloid was first isolated by Kondo and Sanada from the stems of Stephania japonica Miers and has subsequently been discovered in S. abyssinica (Dill. and Rich.) Walp. The alkaloid was originally stated to be optically inactive but more recent determinations show [α]25D ~ 21° (c 1.0, CHC13). The original formula of ClsH2903N has also been altered to that given above. The ultraviolet spectrum in EtOH has two absorption maxima at 205 and 285 mil. The base yields a monoacetate, m.p. 150°C. The structure has been determined primarily from the mass spectrum.

참고 문헌

Kondo, Sanada., J. Pharrn. Soc., Japan, 44, 5 (1924)
Kondo, Sanada., ibid, 47, 31, 126 (1927)
Kondo, Sanada., ibid, 48,163 (1928)
Tomita et ai., Tetrahedron Lett., 3605 (1964)
de Waal, Prinsloo, Arndt., ibid, 6169 (1966)
Mass spectrum:
Tomita, Kato, Ibuka., Tetrahedron Lett., 1019 (1965)

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