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O-아미노아조톨루엔

O-아미노아조톨루엔
O-아미노아조톨루엔 구조식 이미지
카스 번호:
97-56-3
한글명:
O-아미노아조톨루엔
동의어(한글):
0-아미노아조톨루엔;4-o-톨릴아조-o-톨루이딘
상품명:
O-AMINOAZOTOLUENE
동의어(영문):
OAAT;o-AT;aat[qr];oaat[qr];o-at[qr];CI 11160;c.i.11160b;fatyellowb;oilyellowc;oilyellowi
CBNumber:
CB5710733
분자식:
C14H15N3
포뮬러 무게:
225.29
MOL 파일:
97-56-3.mol

O-아미노아조톨루엔 속성

녹는점
101-102 °C
끓는 점
356.8°C (rough estimate)
밀도
1.1303 (rough estimate)
굴절률
1.5770 (estimate)
저장 조건
2-8°C
물리적 상태
Powder
색상 색인 번호
11160
색상
Red-brown
수소이온지수(pH)
pH : 1.4~2.8
Merck
14,420
BRN
6506005
CAS 데이터베이스
97-56-3(CAS DataBase Reference)
NIST
Benzenamine, 2-methyl-4-[(2-methylphenyl)azo]-(97-56-3)
EPA
Benzenamine, 2-methyl-4-[(2-methylphenyl) azo]-(97-56-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T
위험 카페고리 넘버 45-22-43-35
안전지침서 53-45-36/37/39-26
유엔번호(UN No.) UN 1789 8/PG 2
WGK 독일 3
RTECS 번호 XU8800000
TSCA Yes
HS 번호 29270000
유해 물질 데이터 97-56-3(Hazardous Substances Data)
그림문자(GHS):
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H350 암을 일으킬 수 있음 (노출되어도 암을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 발암성 물질 구분 1A, 1B 위험
예방조치문구:
P201 사용 전 취급 설명서를 확보하시오.
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.
P405 밀봉하여 저장하시오.

O-아미노아조톨루엔 C화학적 특성, 용도, 생산

화학적 성질

red-brown crystalline powder

화학적 성질

Aminoazotoluene forms golden yellow or reddish-brown crystalline solid.

용도

Coloring oils, fats and waxes; manufacture of pigments. Chemical intermediate for the production of dyes.

일반 설명

Reddish-brown to golden crystals; orangish red powder. Odorless.

공기와 물의 반응

Dust may form an explosive mixture in air. Insoluble in water.

반응 프로필

O-AMINOAZOTOLUENE is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides. O-AMINOAZOTOLUENE is sensitive to prolonged exposure to heat. O-AMINOAZOTOLUENE is incompatible with strong oxidizing agents.

위험도

Possible carcinogen.

화재위험

Flash point data for O-AMINOAZOTOLUENE are not available. O-AMINOAZOTOLUENE is probably combustible.

Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by ingestion. Moderately toxic by subcutaneous route. An experimental teratogen. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also AROMATIC AMINES.

잠재적 노출

An azo compound used in dyes, medicines; as a colorant in shoe polishes and other wax-based polishes.

Carcinogenicity

o-Aminoazotoluene is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

운송 방법

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Purification Methods

Recrystallise the dye twice from EtOH, once from *benzene, then dry it in an Abderhalden drying apparatus. [Cilento J Am Chem Soc 74 968 1952, Sawicki J Org Chem 21 605 1956, Beilstein 16 H 334, 16 I 322, 16 II 178, 16 III 386, 16 IV 525.] CARCINOGENIC.

비 호환성

Dust may form explosive mixture in air. Azo compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides. This chemical is sensitive to prolonged exposure to heat. This chemical is incompatible with strong oxidizing agents.

법규

Environmental Protection Agency (EPA)
Emergency Planning and Community Right-To-Know Act
Toxics Release Inventory: Listed substance subject to reporting requirements.

O-아미노아조톨루엔 준비 용품 및 원자재

원자재

준비 용품


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