유로퓸

유로퓸
유로퓸 구조식 이미지
카스 번호:
7440-53-1
한글명:
유로퓸
동의어(한글):
유로퓸;유로퓸(EUROPIUM)
상품명:
EUROPIUM
동의어(영문):
Eu;EUROPIUM;EU000200;EU005110;EU006010;Europium rod;Europium foil;europium atom;EUROPIUM METAL;Europium ingot
CBNumber:
CB5726440
분자식:
Eu
포뮬러 무게:
151.96
MOL 파일:
7440-53-1.mol

유로퓸 속성

녹는점
822 °C (lit.)
끓는 점
1527 °C (lit.)
밀도
5.24 g/mL at 25 °C (lit.)
용해도
reacts with H2O
물리적 상태
잉곳 형태
색상
실버/그레이
Specific Gravity
5.24
비저항
81 μΩ-cm, 20°C
수용성
물과 반응합니다.
감도
Air & Moisture Sensitive
Merck
13,3937
노출 한도
ACGIH: TWA 2 ppm; STEL 4 ppm
OSHA: TWA 2 ppm(5 mg/m3)
NIOSH: IDLH 25 ppm; TWA 2 ppm(5 mg/m3); STEL 4 ppm(10 mg/m3)
InChI
InChI=1S/Eu
InChIKey
OGPBJKLSAFTDLK-UHFFFAOYSA-N
SMILES
[Eu]
CAS 데이터베이스
7440-53-1(CAS DataBase Reference)
EPA
Europium (7440-53-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F,C
위험 카페고리 넘버 14/15-17-34
안전지침서 43-7/8-45-36/37/39-27-26-23
유엔번호(UN No.) UN 2813 4.3/PG 2
WGK 독일 3
F 고인화성물질 1-10
TSCA Yes
위험 등급 4.1
포장분류 II
HS 번호 28053090
기존화학 물질 KE-14095
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H250 공기에 노출되면 스스로 발화함 자연발화성 액체;자연발화성 고체 구분 1 위험 GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
예방조치문구:
P222 공기에 접촉하지 마시오.
P231 불활성 기체 하에서 취급하고,
P422 적절한 물질을(를) 충진하여 보관하시오.
NFPA 704
0
3 0

유로퓸 C화학적 특성, 용도, 생산

화학적 성질

grey ingots

물리적 성질

Europium is one of the most rare of the rare-earths. Its abundance on Earth is only 1.1ppm. It is a soft, shiny, steel-gray metal that is quite ductile and malleable, which means it canbe worked and formed into many shapes. It looks like and feels like the element lead (Pb), butis somewhat heavier. It is the most chemically active of all the rare-earths.
Europium’s melting point is 822°C, its boiling point is 1,529°C, and its density is 5.243g/cm3.

Isotopes

There are a total of 45 isotopes of europium. Two are considered stable andaccount for 100% of the europium found on Earth: Eu-151 (47.81%) and Eu-153(52.19%). All the other 53 isotopes are radioactive and artificially produced, primarily through electron capture.

Origin of Name

Named for the continent of Europe.

출처

Europium is the 13th most abundant of all the rare-earths and the 55th most abundantelement on Earth. More europium exists on Earth than all the gold and silver deposits. Likemany other rare-earths, europium is found in deposits of monazite, bastnasite, cerite, andallanite ores located in the river sands of India and Brazil and in the beach sand of Florida.It has proven difficult to separate europium from other rare-earths. Today, the ion-exchange process is used to extract europium from the other rare-earths found in monazite sand(ore).

역사

In 1890 Boisbaudran obtained basic fractions from samarium-gadolinium concentrates that had spark spectral lines not accounted for by samarium or gadolinium. These lines subsequently have been shown to belong to europium. The discovery of Europium is generally credited to Demarcay, who separated the rare earth in reasonably pure form in 1901. The pure metal was not isolated until recent years. Europium is now prepared by mixing Eu2O3 with a 10% excess of lanthanum metal and heating the mixture in a tantalum crucible under high vacuum. The element is collected as a silvery-white metallic deposit on the walls of the crucible. As with other rare-earth metals, except for lanthanum, europium ignites in air at about 150 to 180°C. Europium is about as hard as lead and is quite ductile. It is the most reactive of the rare-earth metals, quickly oxidizing in air. It resembles calcium in its reaction with water. Bastnasite and monazite are the principal ores containing europium. Europium has been identified spectroscopically in the sun and certain stars. Europium isotopes are good neutron absorbers and are being studied for use in nuclear control applications. Europium oxide is now widely used as a phosphor activator and europium-activated yttrium vanadate is in commercial use as the red phosphor in color TV tubes. Europiumdoped plastic has been used as a laser material. With the development of ion-exchange techniques and special processes, the cost of the metal has been greatly reduced in recent years. Natural europium contains two stable isotopes. Thirty-five other radioactive isotopes and isomers are known. Europium is one of the rarest and most costly of the rare-earth metals. It is priced at about $60/g (99.9% pure).

Characteristics

Pure europium will slowly oxidize in air at room temperature and will produce hydrogenwhen placed in water. It will ignite spontaneously if the air temperature is over 150°C. Insome ways europium resembles the elements calcium, strontium, and barium found in group2 of the periodic table.

용도

There are only a few commercial uses for europium. Europium oxide, (Eu2O3), a compoundof europium, is added to infra-sensitive phosphors to enhance the red colors on TVand computer-monitor picture tubes. It is also added to fluorescent light tubes to increasetheir efficiency, as well as to some materials to make lasers. Since it is a good neutron absorber,it is part of nuclear reactor control rods. Europium is an additive to the glue used on postagestamps, thus making it possible for the electronic sorting machines in U.S. postal offices to“read” the stamps.

정의

A silvery element of the lanthanoid series of metals. It occurs in association with other lanthanoids. Its main use is in a mixture of europium and yttrium oxides widely employed as the red phosphor in television screens. The metal is used in some superconducting alloys. Symbol: Eu; m.p. 822°C; b.p. 1597°C; r.d. 5.23 (25°C); p.n. 63; r.a.m. 151.965.

위험도

Europium is very reactive and, in powder form, may burst into flames spontaneously atroom temperature. Most of the salts of europium are toxic when inhaled or ingested.

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