마마닌

마마닌
마마닌 구조식 이미지
카스 번호:
60394-92-5
한글명:
마마닌
동의어(한글):
마마닌
상품명:
mamanine
동의어(영문):
mamanine;6-[(1S,9aβ)-Octahydro-1β-(hydroxymethyl)-2H-quinolizine-3β-yl]pyridine-2(1H)-one;2(1H)-Pyridinone, 6-[(1R,3S,9aS)-octahydro-1-(hydroxymethyl)-2H-quinolizin-3-yl]-, rel-(+)-
CBNumber:
CB61371901
분자식:
C15H22N2O2
포뮬러 무게:
262.35
MOL 파일:
60394-92-5.mol

마마닌 속성

녹는점
17l-2°C

안전

마마닌 C화학적 특성, 용도, 생산

개요

This novel alkaloid occurs in the bark of Sophora chrysophylla and is obtained in the form of colourless crystals of the dihydrate which have the above melting point after prior melting at 100-4°C followed by resolidification. The base has been characterized as the crystalline cyclohexylsulphonate, m.p. 245-252°C and the diacetate which forms colourless needles that decompose on standing at room temperature. The free base is optically active with a specific rotation of [α]24.3/sup>D + 31.7° (c 2.32, EtOH). Mamaine is an intermediate in a previously unknown biogenetic pathway of the Sophora alkaloids (cf. Pohakuline).

참고 문헌

Kadooka et al., Tetrahedron, 32, 919 (1976)

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