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Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) 구조식 이미지
카스 번호:
373650-12-5
상품명:
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
동의어(영문):
RU(OAC)2[(S)-SEGPHOS];(S)-Ru(OAc)2(SEGPHOS);(S)-Ru(OAc)2(SEGPHOS(R));Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-be...;Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II);Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II);Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos];Diacetoxyruthenium, [4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl )-1,3-benzodioxol-5-yl]-diphenyl-phosphane;Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)]
CBNumber:
CB71181064
분자식:
C38H28O4P2.C4H6O4Ru
포뮬러 무게:
829.741
MOL 파일:
373650-12-5.mol
MSDS 파일:
SDS

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) 속성

녹는점
>100°C
저장 조건
2-8°C
물리적 상태
고체
물리적 상태
단단한 모양
색상
노란색에서 검정색으로
감도
air sensitive

안전

WGK 독일 3

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) C화학적 특성, 용도, 생산

용도

(S)-Ru(OAc)2(SEGPHOS?) can be used as a catalyst:
  • To prepare highly chemo, enantio, and diastereoselective primary β-amino lactams by asymmetric reductive amination of racemic β-keto lactams.
  • To synthesize chiral primary diarylmethylamines and sterically bulky benzylamines from diaryl and sterically hindered ketones via asymmetric reductive amination reaction.
  • For the conversion of levulinic acid to optically active γ-valerolactone via asymmetric hydrogenation reaction.

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) 준비 용품 및 원자재

원자재

준비 용품

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) 공급 업체

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Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) 관련 검색:

Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos]　 Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Dichloro(cycloocta-1,5-diene)ruthenium(II) Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II) Dichloro(2-pyridinecarboxylato)gold (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
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