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1-TRIMETHYLSILOXY-1,3-BUTADIENE C화학적 특성, 용도, 생산
화학적 성질
clear light yellow liquid
물리적 성질
bp 131 °C, bp 49.5 °C/25 mmHg; d 0.811 g cm?3.
용도
1-Trimethylsiloxy-1,3-butadiene is a diene used in the Diels-Alder reaction.
일반 설명
Mechanism of Diels-Alder reaction between 1-(trimethylsiloxy)-1,3-butadiene and 4,6-dinitrobenzofuroxan has been studied using state-of-the-art computational methods.
Purification Methods
Purify it by fractional distillation and collect the fractions with the required 1H NMR. Store it under N2 — it is a flammable and moisture-sensitive liquid. [Caseau et al. Bull Soc Chim Fr 16658 1972, Belge Patent 670,769, Chem Abstr 65 5487d 1966.]