(+)-ISOPINOCAMPHEOL

(+)-ISOPINOCAMPHEOL 구조식 이미지
카스 번호:
27779-29-9
상품명:
(+)-ISOPINOCAMPHEOL
동의어(영문):
Nsc167499;3-PINANOL;(+)-ISOPINOCAMPHEOL;(+)-Isopinocampheol;ISOPINOCAMPHEOL, (+)-;3-Pinanol, stereoisomer;ISOPINOCAMPHEOL, (-)-(SG);(1S,2S,3S,5R)-(+)-IsopinocaMpheol 98%;(1s,2s,3s,5r)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol;(1S,3R,4R,5R)-4,6,6-trimethylbicyclo[3.1.1]heptan-3-ol
CBNumber:
CB8441753
분자식:
C10H18O
포뮬러 무게:
154.25
MOL 파일:
27779-29-9.mol

(+)-ISOPINOCAMPHEOL 속성

녹는점
52-55 °C
끓는 점
219 °C(lit.)
밀도
0.8389 (rough estimate)
굴절률
1.4710 (estimate)
인화점
93 °C
산도 계수 (pKa)
15.35±0.60(Predicted)
LogP
2.805 (est)

안전

WGK 독일 3

(+)-ISOPINOCAMPHEOL C화학적 특성, 용도, 생산

용도

(1S,2S,3S,5R)-(+)-Isopinocampheol may be used in the preparation of
  • thermotropic chiral nematic side-chain copolymers
  • ortho-(diphenylphosphino)phenylphosphonous acid di[(1S,2S,3S,5R)-2,6,6-trimethyl-bicyclo[3.1.1]-hept-3-yl]ester, a phosphino-phosphonite ligand
  • O,O′bis[(1S,2S,3S,5R)2,6,6-trimethylbicyclo[3.1.1]hept-3-yl] dithiophosphoric acid, a bioactive compound with antifungal effect

일반 설명

(1S,2S,3S,5R)-(+)-Isopinocampheol is a chiral terpenol.

Purification Methods

Dissolve it in Et2O, dry over MgSO4, filter, evaporate, then recrystallise it from pet ether. Also recrystallise it from aqueous EtOH and distil it in a vacuum. [Kergomard & Geneix Bull Soc Chim Fr 394 1958, Zweifel & Brown J Am Chem Soc 86 393 1964.] The 3,4-dinitrobenzoyl derivative has m 100-101o, the phenylcarbamoyl derivative has m 137-138o and the acid -phthalate has m 125-126o. [Beilstein 6 III 282, 283.]

(+)-ISOPINOCAMPHEOL 준비 용품 및 원자재

원자재

준비 용품


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