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ChemicalBook >> CAS DataBase List >>Dicumyl peroxide

Dicumyl peroxide suppliers

Dicumyl peroxide

CAS:
80-43-3
MF:
C18H22O2
MW:
270.37

Company Type

Properties

Melting point:
39-41 °C (lit.)
Boiling point:
130°C
Density 
1.56 g/mL at 25 °C (lit.)
vapor density 
9.3 (vs air)
vapor pressure 
15.4 mm Hg ( 38 °C)
refractive index 
1.5360
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form 
flakes
color 
White
Water Solubility 
insoluble
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
2056090
Stability:
Reacts violently with reducing agents, heavy metals, concentrated acids, concentrated bases. May ignite organic materials on contact. May decompose violently upon exposure to sunlight or if heated. Incompatible with strong oxidizing agents.
LogP
5.6 at 25℃

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07,GHS08,GHS09
Signal word 
Danger
Hazard statements 
H242-H315-H319-H360D-H411
Precautionary statements 
P210-P235-P273-P280-P308+P313-P370+P378
Hazard Codes 
O,Xi,N,Xn
Risk Statements 
7-36/38-51/53-36/37/38-20
Safety Statements 
14-3/7-36/37/39-61-14A-45-26-36-17
RIDADR 
UN 3110 5.2
WGK Germany 
2
RTECS 
SD8150000
4.2
TSCA 
Yes
HazardClass 
5.2
PackingGroup 
II
HS Code 
29096000
Toxicity
LD50 orally in Rabbit: 4100 mg/kg

Use

The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. Dicumyl peroxide is unlikely that this derivative would be particularly unstable compared to other peroxides in it's class, Bretherick 2nd ed., p 44 1979.

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