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Molybdenum hexacarbonyl

CAS:
13939-06-5
MF:
C6MoO6
MW:
264

Properties

Melting point:
150 °C (dec.) (lit.)
Boiling point:
156 °C (lit.)
Density 
1.96 g/mL at 25 °C (lit.)
vapor density 
9.1 (vs air)
vapor pressure 
0.13 hPa (20 °C)
storage temp. 
Store at <= 20°C.
solubility 
Slightly soluble in tetrahydrofuran, diglyme and acetonitrile.
form 
crystal
color 
white
Specific Gravity
1.960
Water Solubility 
insoluble
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
InChIKey
KMKBZNSIJQWHJA-UHFFFAOYSA-N

Safety Information

Symbol(GHS) 

GHS06
Signal word 
Danger
Hazard statements 
H300-H310-H330-H300+H310+H330
Precautionary statements 
P260-P264-P280-P284-P301+P310-P302+P350-P310-P280f-P302+P352-P304+P340
Hazard Codes 
T+,Xi
Risk Statements 
26/27/28
Safety Statements 
36/37/39-45-36/37-28A-22
RIDADR 
UN 3466 6.1/PG 2
WGK Germany 
3
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29310095

Use

Molybdenum hexacarbonyl is a highly toxicsubstance. It is listed in Toxic SubstanceControl Act. Acute symptoms includeheadache, dizziness, nausea, vomiting, andfever. Because of its low vapor pressure,the risk of exposure of this compound,however, by inhalation is lower than thatfrom the volatile tetra- or pentacoordinatedmetal carbonyls. Ingestion of the compoundcan cause death. Absorption of its solutionthrough skin may cause severe poisoning,manifesting the same effects as those fromother routes of exposure.

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