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ChemicalBook >> CAS DataBase List >>Diethyl ether

Diethyl ether suppliers

Diethyl ether

CAS:
60-29-7
MF:
C4H10O
MW:
74.12

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Properties

Melting point:
-116 °C
Boiling point:
34.6 °C(lit.)
Density 
0.714
vapor density 
2.6 (vs air)
vapor pressure 
28.69 psi ( 55 °C)
refractive index 
n20/D 1.3530(lit.)
Flash point:
-40 °F
storage temp. 
Store at RT.
solubility 
Soluble in water, miscible with ethanol (96 per cent), with methylene chloride and with fatty oils. It is highly flammable.
form 
Liquid
Specific Gravity
0.714 (20/4℃) ; 0.712 (25℃)
Odor
Pungent odor detectable at 0.33 ppm
Relative polarity
2.9
explosive limit
1.7-36%(V)
Water Solubility 
69 g/L (20 ºC)
FreezingPoint 
-116.3℃
Merck 
14,3806
Henry's Law Constant
12.50(x 10-4 atm?m3/mol at 25 °C) (Signer et al., 1969)
Exposure limits
TLV-TWA 1200 mg/m3 (400 ppm) (ACGIH and OSHA); STEL 1500 mg/m3 (500 ppm) (ACGIH).
Dielectric constant
4.0(40℃)
Stability:
Stable, but light-sensitive, sensitive to air. May contain BHT (2,6-di-tert-butyl-4-methylphenol) as a stabilizer. Substances to be avoided include zinc, halogens, halogen-halogen compounds, nonmetals, nonmetallic oxyhalides, strong oxidizing agents, chromyl chloride, turpentine oils, turps substitutes, nitrates, metallic chlorides. Extre
LogP
0.890

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word 
Danger
Hazard statements 
H224-H302-H336
Precautionary statements 
P210-P233-P240-P241-P301+P312-P403+P233
Hazard Codes 
F+,Xn,T,F
Risk Statements 
12-19-22-66-67-39/23/24/25-23/24/25-11
Safety Statements 
9-16-29-33-45-36/37-7
RIDADR 
UN 1155 3/PG 1
WGK Germany 
1
RTECS 
KI5775000
10
Autoignition Temperature
160 °C
TSCA 
Yes
HS Code 
2909 11 00
HazardClass 
3
PackingGroup 
I
Toxicity
LD50 oral (rat) 1215 mg/kg
LC50 inhal (rat) 73,000 ppm (2 h)
PEL (OSHA) 400 ppm

STEL (ACGIH) 500 ppm
IDLA
1,900 ppm [10% LEL]

Use

The acute toxicity of diethyl ether is low. Inhalation of high concentrations can cause sedation, unconsciousness, and respiratory paralysis. These effects are usually reversible upon cessation of exposure. Diethyl ether is mildly irritating to the eyes and skin, but does not generally cause irreversible damage. Repeated contact can cause dryness and cracking of the skin due to removal of skin oils. The liquid is not readily absorbed through the skin, in part because of its high volatility. Diethyl ether is slightly toxic by ingestion. Diethyl ether is regarded as having adequate warning properties. There is no evidence for carcinogenicity of diethyl ether, and no reproductive effects have been reported. Chronic exposure to diethyl ether vapor may lead to loss of appetite, exhaustion, drowsiness, dizziness, and other central nervous system effects.

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