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ChemicalBook >> CAS DataBase List >>ETHION

ETHION suppliers

ETHION

CAS:
563-12-2
MF:
C9H22O4P2S4
MW:
384.46

Company Type

Properties

Melting point:
-13 to -12°
Boiling point:
164~165℃ (0.3mmHg)
Density 
d420 1.220
vapor pressure 
2.0 x 10-4 Pa (25 °C)
refractive index 
nD20 1.5490
storage temp. 
0-6°C
solubility 
Chloroform (Slightly), DMSO (Slightly)
Water Solubility 
2 mg l-1 (25 °C)
form 
liquid
Merck 
13,3772
JECFA Number
85
BRN 
1804530
Exposure limits
NIOSH REL: TWA 0.4 mg/m3; ACGIH TLV: TWA 0.4 mg/m3.

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictograms
GHS06,GHS09
Signal word 
Danger
Hazard statements 
H301-H312-H410
Precautionary statements 
P273-P280-P301+P310+P330-P302+P352+P312
Hazard Codes 
T,N
Risk Statements 
21-25-50/53
Safety Statements 
25-36/37-45-60-61-23
RIDADR 
3018
WGK Germany 
3
RTECS 
TE4550000
HazardClass 
6.1(a)
PackingGroup 
II
Toxicity
LD50 in female, male rats (mg/kg): 27, 65 orally; 62, 245 dermally (Gaines)

Use

Biological. Ethion degraded in lagoonal sediments obtained at various sites in the Indian River between Cape Kennedy and Vero Beach, FL. In 14 sediment samples enriched with ethion, 8 exhibited iron sulfide (precursor hydrogen sulfide) production following 20 days of incubation at room temperature. The bacteria responsible for the degradation of ethion, a reducing agent, was tentatively identified as Clostridium (Sherman et al., 1974). Soil. The half-lives of ethion in an organic soil varied from 16 to 49 weeks; however, repeated applications each spring resulted in increased residues of unreacted ethion (Chapman et al., 1984). Photolytic. Ethion in hexane did not exhibit absorption at UV wavelengths >260 nm (Gore et al., 1971). Chemical/Physical. Emits toxic fumes of phosphorus and sulfur oxides when heated to decomposition (Sax and Lewis, 1987; Lewis, 1990). The hydrolysis half-lives of ethion in a sterile 1% ethanol/water solution at 25°C and pH values of 4.5, 5.0, 6.0, 7.0 and 8.0 were 99, 63, 58, 24 and 8.4 weeks, respectively (Chapman and Cole, 1982).

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