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ChemicalBook >> CAS DataBase List >>Methyl bromide

Methyl bromide suppliers

Methyl bromide

CAS:
74-83-9
MF:
CH3Br
MW:
94.94

Company Type

Properties

Melting point:
−94 °C(lit.)
Boiling point:
4 °C(lit.)
Density 
1.7 g/cm3
vapor density 
3.3 (20 °C, vs air)
vapor pressure 
1420 mm Hg ( 20 °C)
refractive index 
1.4432
Flash point:
-34 °C
storage temp. 
2-8°C
solubility 
water: soluble
form 
Colorless gas
explosive limit
~16%
Water Solubility 
1.522 g/100 mL
Merck 
13,6056
Henry's Law Constant
0.72 at 21 °C (Gan and Yates, 1996)
Dielectric constant
9.8(0℃)
Exposure limits
NIOSH REL: IDLH 250 ppm; OSHA PEL: C 20 ppm; ACGIH TLV: TWA 5 ppm.
Stability:
Stable. Incompatible with oxidizing agents, strong acids. This is an ozone-depleting chemical, and its use is restricted in many countries.
LogP
1.190

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08,GHS09,GHS02,GHS07
Signal word 
Danger
Hazard statements 
H225-H301+H311+H331-H370-H302+H332-H315-H319-H335-H336-H341-H373-H400-H420-H280-H301+H331
Precautionary statements 
P210-P280-P302+P352+P312-P304+P340+P312-P370+P378-P403+P235-P261-P273-P281-P305+P351+P338-P301+P310-P311
Hazard Codes 
T,N,Xn,F,F+
Risk Statements 
23/25-36/37/38-48/20-50-59-68-38-20/22-11-67-66-19-12-39/23/24/25-23/24/25
Safety Statements 
15-27-36/39-38-45-59-61-36/37-26-24-16-7
RIDADR 
UN 1062 2.3
WGK Germany 
3
RTECS 
PA4900000
DOT Classification
2.3, Hazard Zone C (Gas poisonous by inhalation)
HazardClass 
2.3
HS Code 
29033990
Toxicity
LC for rats in air (6 hrs): 514 ppm (Irish)
IDLA
250 ppm

Use

Methyl bromide is used as a fumigant and pesticide. Exposure may occur during fumigation activities. Methyl bromide is a broad-spectrum fumigant that has been used around the world since the 1930s as a pre-plant soil fumigant to control insects, pathogens, and weeds, and to control insects in buildings and in commodities. It is also used for quarantine and pre-shipment applications. Methyl bromide is one of the very few chemicals that were approved for broad-spectrum use in agriculture and pest control. The dominant use of methyl bromide worldwide is for pre-planting soil fumigation. Methyl bromide is the most effective soil fumigant for killing plant pests, its use is being phased out because its emissions from soil can lead to stratospheric ozone depletion. 1992, Parties to the Montreal Protocol on Substances that Deplete the Ozone Layer recognized that methyl bromide has an ozone-depleting potential (ODP); thus it is identified as an ozone-depleting substance.

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