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ChemicalBook >> CAS DataBase List >>Methylamine

Methylamine suppliers

Methylamine

CAS:
74-89-5
MF:
CH5N
MW:
31.06

Properties

Melting point:
-93 °C(lit.)
Boiling point:
-6.3 °C(lit.)
Density 
0.785 g/mL at 25 °C
vapor density 
1.08 (20 °C, vs air)
vapor pressure 
27 psi ( 20 °C)
refractive index 
n20/D 1.371
Flash point:
61 °F
storage temp. 
Store below +30°C.
solubility 
highly soluble in water (108g/100g) at 25°C; soluble in alcohol and miscible with ether; HCl salt is soluble in water and absolute alcohol; compound is insoluble in chloroform, acetone, ether, and ethyl acetate
pka
10.63(at 25℃)
form 
Gas
Specific Gravity
0.901 (20℃/4℃) (40% Soln.)
PH
14 (H2O, 20°C)
explosive limit
4.9-20.8%
Odor Threshold
0.035ppm
Water Solubility 
Miscible with water, ethanol, benzene, acetone and ether.
Merck 
14,6014
BRN 
741851
Henry's Law Constant
(x 10-5 atm?m3/mol): 1.11 at 25 °C (Christie and Crisp, 1967)
Exposure limits
TLV-TWA 10 ppm (~12.3 mg/m3)(ACGIH, MSHA, and OSHA); IDLH 100 ppm (NIOSH).
Dielectric constant
10.0(18℃)
Stability:
Stable. Highly flammable. Note wide explosion limits. Incompatible with oxidizing agents, acids, alkalies, alkaline earth metals, copper and its alloys, zinc and its alloys.
LogP
-0.570

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS07
Signal word 
Danger
Hazard statements 
H225-H314-H335
Precautionary statements 
P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
Hazard Codes 
F+,Xn,C,F,T
Risk Statements 
12-20-37/38-41-34-20/22-11-39/23/24/25-36/37/38-23/24/25-40-19
Safety Statements 
7-16-26-36/37-45-29-36/37/39-3/7-3-39-33
RIDADR 
UN 3286 3/PG 2
WGK Germany 
2
RTECS 
PF6300000
4.5-31
Autoignition Temperature
806 °F
TSCA 
Yes
DOT Classification
2.1 (Flammable gas)
HazardClass 
3
PackingGroup 
II
HS Code 
29211100
Toxicity
LD50 orally in rats: 100-200 mg/kg (Kinney); LC50 in rats: 0.448 ml/l (Sarkar, Sastry)
IDLA
100 ppm

Use

Methylamine is an important kind of fatty amines organic chemicals and is used in a variety of industries such as manufacture of dyestuffs, treatment of cellulose, acetate rayon, as fuel additive, rocket propellant, and leather tanning processes. It can be used in the synthesis of the N-methyl-chloroacetamide that is the intermediate of the organic phosphorus insecticide dimethoate and omethoate; synthesis of the intermediate of the monocrotophos, α-chloro acetoacetyl methylamine; synthesis of the intermediates of carbamate pesticide, carbamoyl chloride and methyl isocyanate; as well as the synthesis of other pesticides varieties such as formamidine, amitraz, and tribenuron, etc. In addition, it can also be used in medicine, rubber, dyes, leather industry and photosensitive materials.

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