VANADIUM(V) TRICHLORIDE OXIDE manufacturers and suppliers

VANADIUM(V) TRICHLORIDE OXIDE suppliers

Properties

Melting point:: −77 °C(lit.)

Boiling point:: 126-127 °C(lit.)

Density: 1.84 g/mL at 25 °C(lit.)

vapor pressure: 13.8 mm Hg ( 20 °C)

refractive index: 1.6300

Flash point:: 126-127°C

solubility: Miscible with benzene, dichloromethane and hexane.

form: Liquid

color: Yellow

Specific Gravity: 1.84

Water Solubility: decomposes in H2O to vanadic acid and HCl; soluble methanol, ether, acetone, acids [KIR83] [MER06]

Sensitive: Moisture Sensitive

Merck: 14,9927

Dielectric constant: 3.6（26℃）

Exposure limits: NIOSH: Ceiling 0.05 mg/m3

LogP: 0 at 20℃

CAS DataBase Reference: 7727-18-6(CAS DataBase Reference)

EPA Substance Registry System: Vanadium, trichlorooxo-, (T-4)- (7727-18-6)

Safety Information

Symbol(GHS): GHS05,GHS06

Signal word: Danger

Hazard statements: H301-H314

Precautionary statements: P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363

Hazard Codes: T

Risk Statements: 14-25-34

Safety Statements: 26-27-28-36/37/39-45

RIDADR: UN 2443 8/PG 2

WGK Germany: 3

RTECS: YW2975000

F: 10-21

TSCA: Yes

HazardClass: 8

PackingGroup: II

Hazardous Substances Data: 7727-18-6(Hazardous Substances Data)

Toxicity: LD50 orally in rats: 0.14 g/kg (Smyth)

Use

VANADIUM(V) TRICHLORIDE OXIDE is incompatible with bases, including amines, with strong oxidizing agents, and with alcohols. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. Combination with sodium metal led to a violent explosion [Bretherick 5th ed., 1995].

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