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ChemicalBook >> CAS DataBase List >> tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate price.
  • $21 - $1739.43
  • Product name: tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
  • CAS: 112741-50-1
  • MF: C21H23NO4
  • MW: 353.41
  • EINECS:627-150-5
  • MDL Number:MFCD00074953
  • Synonyms:(2S,3R)-6-Oxo-2,3-diphenyl-morpholine-4-carboxylic acid tert-butyl ester;(5S,6R)-(+)-4-Boc-5,6-diphenyl-2-Morpholinone, 99%;(2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylMorpholine;(5R,6S)-N-Boc-5,6-diphenyl-2-morpholinone;tert-butyl (2S,3R)-6-oxo-2,3-diphenylMorpholine-4-carboxylate;(2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylMorpholine;(2S, 3R) - (+) - N- t-butoxycarbonyl-6-oxo-2,3-diphenyl-Morpholine;(2S,3R)-6-Oxo-2,3-diphenyl-4-morpholinecarboxylic Acid 1,1-Dimethylethyl Ester
Price28 Properties Safety Information Description
28 prices
Selected condition：
Brand
  • Abosyn
  • AK Scientific
  • Alichem
  • Ambeed
  • American Custom Chemicals Corporation
  • Biosynth Carbosynth
  • Chemenu
  • Chem-Impex
  • Crysdot
  • Matrix Scientific
  • Sigma-Aldrich
  • TRC
Package
  • 250mg
  • 500mg
  • 1g
  • 2g
  • 2.5g
  • 5g
  • 10g
  • 25g
  • ManufacturerAbosyn
  • Product number61-1049
  • Product description(2S,3R)-tert-butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95-98%
  • Packaging1g
  • Price$400
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberX9028
  • Product descriptionN-Boc-(2S,3R)-(+)-6-Oxo-2,3-diphenyl-4-morpholinecarboxylate
  • Packaging25g
  • Price$852
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number112741501
  • Product descriptiontert-Butyl(2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
  • Packaging10g
  • Price$285.32
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA488941
  • Product description(2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging250mg
  • Price$21
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA488941
  • Product description(2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging1g
  • Price$47
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA488941
  • Product description(2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging5g
  • Price$135
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA488941
  • Product description(2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging10g
  • Price$226
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA488941
  • Product description(2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging25g
  • Price$495
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0014687
  • Product descriptionN-BOC(2S, 3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINE CARBOXYLATE 95.00%
  • Packaging1G
  • Price$958.65
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0014687
  • Product descriptionN-BOC(2S, 3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINE CARBOXYLATE 95.00%
  • Packaging5G
  • Price$1739.43
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB63306
  • Product description(2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate
  • Packaging500mg
  • Price$190
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB63306
  • Product description(2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate
  • Packaging1g
  • Price$300
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB63306
  • Product description(2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate
  • Packaging2g
  • Price$480
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB63306
  • Product description(2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate
  • Packaging5G
  • Price$825
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB63306
  • Product description(2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate
  • Packaging10g
  • Price$1105
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM105764
  • Product descriptiontert-butyl(2S,3R)-6-oxo-2,3-diphenylMorpholine-4-carboxylate 95%
  • Packaging5g
  • Price$184
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Abosyn 61-1049 (2S,3R)-tert-butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95-98% 1g $400 2021-12-16 Buy
AK Scientific X9028 N-Boc-(2S,3R)-(+)-6-Oxo-2,3-diphenyl-4-morpholinecarboxylate 25g $852 2021-12-16 Buy
Alichem 112741501 tert-Butyl(2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate 10g $285.32 2021-12-16 Buy
Ambeed A488941 (2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 250mg $21 2021-12-16 Buy
Ambeed A488941 (2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 1g $47 2021-12-16 Buy
Ambeed A488941 (2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 5g $135 2021-12-16 Buy
Ambeed A488941 (2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 10g $226 2021-12-16 Buy
Ambeed A488941 (2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 25g $495 2021-12-16 Buy
American Custom Chemicals Corporation CHM0014687 N-BOC(2S, 3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINE CARBOXYLATE 95.00% 1G $958.65 2021-12-16 Buy
American Custom Chemicals Corporation CHM0014687 N-BOC(2S, 3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINE CARBOXYLATE 95.00% 5G $1739.43 2021-12-16 Buy
Biosynth Carbosynth FB63306 (2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate 500mg $190 2021-12-16 Buy
Biosynth Carbosynth FB63306 (2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate 1g $300 2021-12-16 Buy
Biosynth Carbosynth FB63306 (2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate 2g $480 2021-12-16 Buy
Biosynth Carbosynth FB63306 (2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate 5G $825 2021-12-16 Buy
Biosynth Carbosynth FB63306 (2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate 10g $1105 2021-12-16 Buy
Chemenu CM105764 tert-butyl(2S,3R)-6-oxo-2,3-diphenylMorpholine-4-carboxylate 95% 5g $184 2021-12-16 Buy
Next Last

Properties

Melting point :206 °C (dec.)(lit.)
Boiling point :509.6±50.0 °C(Predicted)
alpha :86 º (c=5.5 in methylene chloride)
Density :1.175±0.06 g/cm3(Predicted)
storage temp. :2-8°C
pka :-3.28±0.60(Predicted)
optical activity :[α]20/D +86°, c = 5.5 in methylene chloride
InChIKey :MRUKRSQUUNYOFK-MOPGFXCFSA-N
CAS DataBase Reference :112741-50-1(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylmorpholine (Williams chiral auxiliary) can be used as a reactant:
  • In the asymmetric synthesis of cylindrospermopsin and related alkaloids via an intramolecular 1,3-dipolar cycloaddition reaction.
  • To synthesize boc-3-(1-methylcyclopropyl)-D-alanine, which is used as an intermediate to prepare 4-fluoroproline-based analogs as potent tripeptide thrombin inhibitors.
  • In the total synthesis of potent hepatotoxic alkaloid 7-epicylindrospermopsin by intramolecular 1,3-dipolar cycloaddition and nitroaldol reaction.
  • To prepare differentially functionalized diaminoglutamic acids via radical reaction of selenide with methyl 2-acetamidoacrylate.

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Suppliers and manufacturers

career henan chemical co
tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
$9.80 /1.79999995231628KG
tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate CAS:112741-50-1
Capot Chemical Co.,Ltd.
Accela ChemBio Inc.
Alchem Pharmtech,Inc.
CONIER CHEM AND PHARMA LIMITED
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd
Dayang Chem (Hangzhou) Co.,Ltd.
Labnetwork lnc.
Hefei TNJ Chemical Industry Co.,Ltd.
SyncoZymes (Shanghai) Co., Ltd.,