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ChemicalBook >> CAS DataBase List >> (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE price.
  • $21 - $1528.67
  • Product name: (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
  • CAS: 135620-04-1
  • MF: C36H52ClMnN2O2
  • MW: 635.2
  • EINECS:
  • MDL Number:MFCD02101663
  • Synonyms:(+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- HEXANEDIAMINO-MN CL;(S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL;(1S,2S)-(+)-(1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene))manganese(III)chloride;(S,S)-Jacobsencat.;(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III)chloride,98%(S,S)-JacobsenCat.;(S,S)(+)N,N'-Bis(3,5-di-tbutylsalicylidene)1,2-chexanediaminomanganese(iii)chlorideco;(S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chlo;(1S,2S)-(+)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]Manganese(III) chloride (S,S)-Jacobsen Cat.
Price19 Properties Safety Information Description
19 prices
Selected condition：
Brand
  • AK Scientific
  • American Custom Chemicals Corporation
  • BLDpharm
  • Chemenu
  • Crysdot
  • Matrix Scientific
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 1g
  • 5G
  • 10g
  • 25G
  • 100g
  • ManufacturerAK Scientific
  • Product numberJ57362
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride
  • Packaging1g
  • Price$30
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ57362
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride
  • Packaging100g
  • Price$720
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0000049
  • Product description(1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE 95.00%
  • Packaging1G
  • Price$641.18
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0000049
  • Product description(1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE 95.00%
  • Packaging5G
  • Price$908.47
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0000049
  • Product description(1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE 95.00%
  • Packaging25G
  • Price$1528.67
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD228424
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98%
  • Packaging1g
  • Price$21
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD228424
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98%
  • Packaging5g
  • Price$73
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD228424
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98%
  • Packaging10g
  • Price$131
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD228424
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98%
  • Packaging25g
  • Price$247
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM282415
  • Product description(S,S)-[N,N''-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 95%
  • Packaging25g
  • Price$370
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD52001301
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 95+%
  • Packaging25g
  • Price$392
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number097952
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride 95+%
  • Packaging1g
  • Price$95
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number097952
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride 95+%
  • Packaging5g
  • Price$252
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number097952
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride 95+%
  • Packaging10g
  • Price$395
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number404454
  • Product description(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging1g
  • Price$34.32
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number404454
  • Product description(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging5g
  • Price$112.2
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific J57362 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 1g $30 2021-12-16 Buy
AK Scientific J57362 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 100g $720 2021-12-16 Buy
American Custom Chemicals Corporation OGM0000049 (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE 95.00% 1G $641.18 2021-12-16 Buy
American Custom Chemicals Corporation OGM0000049 (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE 95.00% 5G $908.47 2021-12-16 Buy
American Custom Chemicals Corporation OGM0000049 (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE 95.00% 25G $1528.67 2021-12-16 Buy
BLDpharm BD228424 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98% 1g $21 2021-12-16 Buy
BLDpharm BD228424 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98% 5g $73 2021-12-16 Buy
BLDpharm BD228424 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98% 10g $131 2021-12-16 Buy
BLDpharm BD228424 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98% 25g $247 2021-12-16 Buy
Chemenu CM282415 (S,S)-[N,N''-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 95% 25g $370 2021-12-16 Buy
Crysdot CD52001301 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 95+% 25g $392 2021-12-16 Buy
Matrix Scientific 097952 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride 95+% 1g $95 2021-12-16 Buy
Matrix Scientific 097952 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride 95+% 5g $252 2021-12-16 Buy
Matrix Scientific 097952 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride 95+% 10g $395 2021-12-16 Buy
Sigma-Aldrich 404454 (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 1g $34.32 2024-03-01 Buy
Sigma-Aldrich 404454 (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 5g $112.2 2024-03-01 Buy
Next Last

Properties

Melting point :330-332 °C(lit.)
storage temp. :Inert atmosphere,Room Temperature
form :Powder
color :brown
InChIKey :VGAJDQCIDNCJQC-JINVCYSXSA-K
CAS DataBase Reference :135620-04-1

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Salen (Mn)-catalyzed asymmetric epoxidation of unfunctionalized olefins.High enantioselectivities and yields are obtained for a variety of substrates,especiallycis-alkenes. A few applications include the synthesis of the taxol side chainandcis-1-amino-2-indanol.Jacobsen′s catalyst has also been used in the asymmetricα-hydroxylation of silyl enol ethers.Catalyst for the enantioselective epoxidation of a variety of olefins.

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Suppliers and manufacturers

career henan chemical co
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
$1.00 /1KG
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE CAS:135620-04-1
Hubei Jusheng Technology Co.,Ltd.
Chongqing Chemdad Co., Ltd
CONIER CHEM AND PHARMA LIMITED
Zhengzhou Alfa Chemical Co.,Ltd
Shanghai UCHEM Inc.
Shaanxi Dideu Medichem Co. Ltd
Dayang Chem (Hangzhou) Co.,Ltd.
Labnetwork lnc.
Alfa Chemistry