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ChemicalBook >> CAS DataBase List >> Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) price.
  • $37.8 - $1685
  • Product name: Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
  • CAS: 220114-32-9
  • MF: C71H74Cl2N2O2P2Ru
  • MW: 1221.3
  • EINECS:
  • MDL Number:MFCD09753026
  • Synonyms:Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II);RuCl2[(R)-DM-BINAP][(R)-DAIPEN];Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl);Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen];RuCl2[(R)-xylbinap][(R)-daipen] RuCl2[(R)-xylbinap][(R)-daipen];RuCl2[(R)-xylbinap][(R)-daipen];Dichloro{(R)-(+)-2,2''-bis[di(3,5-xylyl)phosphino]-1,1''-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen];dichloro{(r)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2r)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(ii)
Price11 Properties Safety Information Description
11 prices
Selected condition：
Brand
  • AK Scientific
  • American Custom Chemicals Corporation
  • Labseeker
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
  • TRC
Package
  • 5MG
  • 50mg
  • 100mg
  • 200mg
  • 250mg
  • 1g
  • 5g
  • ManufacturerAK Scientific
  • Product number4164AL
  • Product description(R)-Daipen
  • Packaging200mg
  • Price$147
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0013142
  • Product descriptionDICHLORO-[(R)-(+)-2,2'-BIS-[DI-(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL]-[(2R)-(-)-1,1-BIS-(4-METHOXYPHENYL)-3-METHYL-1,2-BUTANEDIAMINE]RUTHENIUM-(II) 95.00%
  • Packaging5MG
  • Price$498.06
  • Updated2021-12-16
  • Buy
  • ManufacturerLabseeker
  • Product numberSC-91645
  • Product descriptionRuCl2[(R)-xylbinap][(R)-daipen] 95
  • Packaging1g
  • Price$975
  • Updated2021-12-16
  • Buy
  • ManufacturerLabseeker
  • Product numberSC-91645
  • Product descriptionRuCl2[(R)-xylbinap][(R)-daipen] 95
  • Packaging5g
  • Price$1685
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number692255
  • Product descriptionRuCl2[(R)?DM?BINAP][(R)?DAIPEN]
  • Packaging100mg
  • Price$37.8
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0212
  • Product descriptionDichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen]
  • Packaging250mg
  • Price$64
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0212
  • Product descriptionDichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen]
  • Packaging1g
  • Price$190
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0212
  • Product descriptionDichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen]
  • Packaging5g
  • Price$474
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberR0133
  • Product descriptionRuCl2[(R)-xylbinap][(R)-daipen]
  • Packaging200mg
  • Price$79
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberR0133
  • Product descriptionRuCl2[(R)-xylbinap][(R)-daipen]
  • Packaging1g
  • Price$268
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberR701565
  • Product descriptionRuCl2[(R)−DM−binap][(R)−daipen]
  • Packaging50mg
  • Price$70
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 4164AL (R)-Daipen 200mg $147 2021-12-16 Buy
American Custom Chemicals Corporation ING0013142 DICHLORO-[(R)-(+)-2,2'-BIS-[DI-(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL]-[(2R)-(-)-1,1-BIS-(4-METHOXYPHENYL)-3-METHYL-1,2-BUTANEDIAMINE]RUTHENIUM-(II) 95.00% 5MG $498.06 2021-12-16 Buy
Labseeker SC-91645 RuCl2[(R)-xylbinap][(R)-daipen] 95 1g $975 2021-12-16 Buy
Labseeker SC-91645 RuCl2[(R)-xylbinap][(R)-daipen] 95 5g $1685 2021-12-16 Buy
Sigma-Aldrich 692255 RuCl2[(R)?DM?BINAP][(R)?DAIPEN] 100mg $37.8 2024-03-01 Buy
Strem Chemicals 44-0212 Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen] 250mg $64 2024-03-01 Buy
Strem Chemicals 44-0212 Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen] 1g $190 2024-03-01 Buy
Strem Chemicals 44-0212 Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen] 5g $474 2024-03-01 Buy
TCI Chemical R0133 RuCl2[(R)-xylbinap][(R)-daipen] 200mg $79 2024-03-01 Buy
TCI Chemical R0133 RuCl2[(R)-xylbinap][(R)-daipen] 1g $268 2024-03-01 Buy
TRC R701565 RuCl2[(R)−DM−binap][(R)−daipen] 50mg $70 2021-12-16 Buy

Properties

Melting point :197-211 °C
storage temp. :2-8°C
form :solid
color :yellow to dark brown or green
Sensitive :air sensitive

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321 Specific treatment (see … on this label).
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.

Description

Chiral RuCl2(diphosphine)?(1,?2-?diamine) complexes catalyzes the asymetrical hydrogenation of amino ketones. E.g., hydrogenation of MeCOCH2NMe2 in presence of trans-?RuCl2[(R)?-?xylbinap]?[(R)?-?daipen] gave 79?% (S)?-?MeCH(OH)?CH2NMe2. This compound was used as a catalyst.

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