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ChemicalBook >> CAS DataBase List >> (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM

(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM

(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM price.
  • $16 - $8610
  • Product name: (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
  • CAS: 301224-40-8
  • MF: C31H37Cl2N2ORu
  • MW: 625.62
  • EINECS:608-446-3
  • MDL Number:MFCD03701614
  • Synonyms:(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM;RUTHENIUM,[1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE]DICHLORO[[2-(1-METHYLETHOXY)PHENYL]METHYLENE];[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(2-isopropoxyphenylmethylene)ruthenium;Hoveyda-Grubbs Catalyst 2nd Generation,(1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium;(1,3-Bis-(2,4,6-triMethylphenyl)-2-iMidazolidinylidene)dichloro (o-isopropylphenylMethylene)rutheniuM;(1,3-DiMesityliMidazolidin-2-ylidene)(2-isopropoxybenzylidene)rutheniuM(VI) chloride;Dichloro(1,3-diMesityl-2-iMidazolidinylidene)(2-isopropoxybenzylidene)rutheniuM;Hoveyda-Grubbs Catalyst 2nd Generation,97%
23 prices
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  • Abosyn
  • AK Scientific
  • Alichem
  • Ambeed
  • American Custom Chemicals Corporation
  • Chemenu
  • ChemScene
  • Sigma-Aldrich
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  • 100mg
  • 0.25g
  • 250mg
  • 500mg
  • 1g
  • 2g
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  • 10g
  • 25g
  • 200g
  • ManufacturerAbosyn
  • Product number61-5932
  • Product description(1,3-dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98+%
  • Packaging0.25g
  • Price$1300
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ97807
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride
  • Packaging250mg
  • Price$81
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number301224408
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride
  • Packaging1g
  • Price$197.96
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number301224408
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride
  • Packaging5g
  • Price$625.21
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA685700
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98%
  • Packaging100mg
  • Price$16
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA685700
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98%
  • Packaging250mg
  • Price$35
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA685700
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98%
  • Packaging1g
  • Price$103
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA685700
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98%
  • Packaging5g
  • Price$473
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA685700
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98%
  • Packaging10g
  • Price$851
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0004327
  • Product descriptionHOVEYDA-GRUBBS CATALYST 2NDGENERATION 95.00%
  • Packaging100MG
  • Price$463.8
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0004327
  • Product descriptionHOVEYDA-GRUBBS CATALYST 2NDGENERATION 95.00%
  • Packaging250MG
  • Price$500
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0004327
  • Product descriptionHOVEYDA-GRUBBS CATALYST 2NDGENERATION 95.00%
  • Packaging1G
  • Price$608
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM102933
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 95+%
  • Packaging200g
  • Price$7875
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-W007938
  • Product descriptionHoveyda-Grubbs2nd ≥98.0%
  • Packaging250mg
  • Price$53
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-W007938
  • Product descriptionHoveyda-Grubbs2nd ≥98.0%
  • Packaging1g
  • Price$145
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-W007938
  • Product descriptionHoveyda-Grubbs2nd ≥98.0%
  • Packaging5g
  • Price$570
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Abosyn 61-5932 (1,3-dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98+% 0.25g $1300 2021-12-16 Buy
AK Scientific J97807 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 250mg $81 2021-12-16 Buy
Alichem 301224408 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 1g $197.96 2021-12-16 Buy
Alichem 301224408 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 5g $625.21 2021-12-16 Buy
Ambeed A685700 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98% 100mg $16 2021-12-16 Buy
Ambeed A685700 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98% 250mg $35 2021-12-16 Buy
Ambeed A685700 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98% 1g $103 2021-12-16 Buy
Ambeed A685700 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98% 5g $473 2021-12-16 Buy
Ambeed A685700 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98% 10g $851 2021-12-16 Buy
American Custom Chemicals Corporation ING0004327 HOVEYDA-GRUBBS CATALYST 2NDGENERATION 95.00% 100MG $463.8 2021-12-16 Buy
American Custom Chemicals Corporation ING0004327 HOVEYDA-GRUBBS CATALYST 2NDGENERATION 95.00% 250MG $500 2021-12-16 Buy
American Custom Chemicals Corporation ING0004327 HOVEYDA-GRUBBS CATALYST 2NDGENERATION 95.00% 1G $608 2021-12-16 Buy
Chemenu CM102933 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 95+% 200g $7875 2021-12-16 Buy
ChemScene CS-W007938 Hoveyda-Grubbs2nd ≥98.0% 250mg $53 2021-12-16 Buy
ChemScene CS-W007938 Hoveyda-Grubbs2nd ≥98.0% 1g $145 2021-12-16 Buy
ChemScene CS-W007938 Hoveyda-Grubbs2nd ≥98.0% 5g $570 2021-12-16 Buy

Properties

Melting point :216-220 °C(lit.)
storage temp. :2-8°C
solubility :Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Slightly)
form :Solid
color :Green to Very Dark Green
Stability :Hygroscopic
InChIKey :ZRPFJAPZDXQHSM-UHFFFAOYSA-L
CAS DataBase Reference :301224-40-8
EPA Substance Registry System :Ruthenium, [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-.kappa.O)phenyl]methylene-.kappa.C]-, (SP-5-41)- (301224-40-8)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H227 Combustible liquid Flammable liquids Category 4 Warning P210, P280, P370+P378, P403+P235,P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P363 Wash contaminated clothing before reuse.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container to..…

Description

It′s a phosphine free version of Grubbs 2nd Generation Catalyst with comparable reactivity, but initiates more readily at lower temperatures. Efficient for metathesis of electron-deficient substrates including fluorinated olefins. Demonstrated in multiple large-scale pharmaceutical applications.
It can be used as a catalyst for olefin cross-metathesis with fluorinated olefins (CM), ring-closing metathesis (RCM), ring-opening metathesis (ROM), and a sequence of a metathesis reaction and subsequent dihydroxylation of the newly formed double bond.

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